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Instruments / Technical Area	Publication Details	Published	Actions
I18-Microfocus Spectroscopy	Selenium uptake from livestock pasture extremely enriched in selenium, molybdenum and uranium: a field and X-ray absorption study Shauna L. Mcloughlin , Richard A. D. Pattrick , J. Frederick W. Mosselmans , Joe Kelleher , Bart E. Van Dongen Soil Systems 7 DOI: 10.3390/soilsystems7010024 Diamond Proposal Number(s): [15475, 15215, 12700] Open Access Show Abstract ▼ Abstract: The agricultural soils of West Limerick, Ireland, contain very localised, extremely high natural Se concentrations that reach levels that are very toxic to grazing livestock. The Carboniferous shales that formed in anoxic deep-water marine environments are the source of the selenium, which, along with the other redox-sensitive elements of molybdenum, uranium, arsenic and vanadium, were mobilised and reprecipitated in post-glacial anoxic marshes. The result has been a history of selenosis and molybdenosis in livestock in this important dairy province. Soils collected at 10–20 cm from five different agricultural sites were analysed, and all yielded concentrations greatly in excess of the safe Se limits of 3–10 mg kg−1; the highest value recorded was 1265.8 mg kg−1 Se. The highest recorded value for Mo in these soils was 1627.5 mg kg−1, and for U, 658.8 mg kg−1. There was a positive correlation between Se, Mo U and organic matter in the soils. Analysis of non-accumulator pasture grasses (Lolium perenne (perennial ryegrass), Festuca arundinacea (tall fescue), Dactylis glomerata (cocksfoot) and Phleum pretense (timothy grass)) revealed the shoot/leaf to contain up to 78.05 mg kg−1 Se while Trifolium repens (white clover) leaves contained 296.15 mg kg−1 Se. An in situ growing experiment using the Se accumulator species Brassica oleracea revealed 971.2 mg kg−1 Se in the leaves of premier kale, which also contained 1000.4 mg kg−1 Mo. Translocation factors (TFs) were generally higher for Mo than Se across all plant species. Combined X-ray absorption near edge spectroscopy (XANES) with micro-X-ray fluorescence (μ-XRF) showed the Se was present in the soil predominantly as the reduced immobile phase, elemental Se (Se0), but also as bioavailable organoselenium species, mainly selenomethionine (SeMet). SeMet was also the main species identified within both the Se non-accumulator and Se accumulator plants. The Se soil–plant system in West Limerick is dominated by SeMet, and uptake into the cattle pasture results in selenosis in the grazing dairy herds. The hyperaccumulating Brassica oleracea species could be used to extract both the Se and Mo to reduce the toxicity of the blighted fields.	Mar 2023
I12-JEEP: Joint Engineering, Environmental and Processing	An experimental procedure to determine the interaction between applied loads and residual stresses Graeme Horne , Matthew Peel , Danie Hattingh , Thomas Connolley , Mike Hart , Joe Kelleher , Shu Yan Zhang , David Smith 9th International Conference on Residual Stresses DOI: 10.4028/www.scientific.net/MSF.768-769.733 Diamond Proposal Number(s): [7729] Show Abstract ▼ Abstract: This paper presents a novel experiment to quantify both the initial residual stress state in a specimen and its redistribution due to plasticity induced by in-situ loading. The rate of relaxation of the residual stress with respect to permanent deformation is a measure of the elastic follow-up associated with the residual stress field. Residual stress measurements were made using high energy dispersive X-ray diffraction. Digital image correlation, verified by strain gauges, was used to measure full-field deformation on the specimen. The specimen was loaded and unloaded in-situ incrementally to promote plasticity, allowing the relaxation rate of the residual stress to be quantified. An elastic follow-up factor was calculated for the residual stress field, that indicated loading conditions of the residual stress field between fixed-displacement and fixed-load.	Sep 2013

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I18-Microfocus Spectroscopy

Selenium uptake from livestock pasture extremely enriched in selenium, molybdenum and uranium: a field and X-ray absorption study

Shauna L. Mcloughlin , Richard A. D. Pattrick , J. Frederick W. Mosselmans , Joe Kelleher , Bart E. Van Dongen

Soil Systems 7

DOI: 10.3390/soilsystems7010024

Diamond Proposal Number(s): [15475, 15215, 12700]

Open Access

Show Abstract ▼

Abstract: The agricultural soils of West Limerick, Ireland, contain very localised, extremely high natural Se concentrations that reach levels that are very toxic to grazing livestock. The Carboniferous shales that formed in anoxic deep-water marine environments are the source of the selenium, which, along with the other redox-sensitive elements of molybdenum, uranium, arsenic and vanadium, were mobilised and reprecipitated in post-glacial anoxic marshes. The result has been a history of selenosis and molybdenosis in livestock in this important dairy province. Soils collected at 10–20 cm from five different agricultural sites were analysed, and all yielded concentrations greatly in excess of the safe Se limits of 3–10 mg kg−1; the highest value recorded was 1265.8 mg kg−1 Se. The highest recorded value for Mo in these soils was 1627.5 mg kg−1, and for U, 658.8 mg kg−1. There was a positive correlation between Se, Mo U and organic matter in the soils. Analysis of non-accumulator pasture grasses (Lolium perenne (perennial ryegrass), Festuca arundinacea (tall fescue), Dactylis glomerata (cocksfoot) and Phleum pretense (timothy grass)) revealed the shoot/leaf to contain up to 78.05 mg kg−1 Se while Trifolium repens (white clover) leaves contained 296.15 mg kg−1 Se. An in situ growing experiment using the Se accumulator species Brassica oleracea revealed 971.2 mg kg−1 Se in the leaves of premier kale, which also contained 1000.4 mg kg−1 Mo. Translocation factors (TFs) were generally higher for Mo than Se across all plant species. Combined X-ray absorption near edge spectroscopy (XANES) with micro-X-ray fluorescence (μ-XRF) showed the Se was present in the soil predominantly as the reduced immobile phase, elemental Se (Se0), but also as bioavailable organoselenium species, mainly selenomethionine (SeMet). SeMet was also the main species identified within both the Se non-accumulator and Se accumulator plants. The Se soil–plant system in West Limerick is dominated by SeMet, and uptake into the cattle pasture results in selenosis in the grazing dairy herds. The hyperaccumulating Brassica oleracea species could be used to extract both the Se and Mo to reduce the toxicity of the blighted fields.

Mar 2023

I12-JEEP: Joint Engineering, Environmental and Processing

An experimental procedure to determine the interaction between applied loads and residual stresses

Graeme Horne , Matthew Peel , Danie Hattingh , Thomas Connolley , Mike Hart , Joe Kelleher , Shu Yan Zhang , David Smith

9th International Conference on Residual Stresses

DOI: 10.4028/www.scientific.net/MSF.768-769.733

Diamond Proposal Number(s): [7729]

Show Abstract ▼

Sep 2013

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