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B18-Core EXAFS	Capping agent, solvent and nanoparticle interactions: driving selectivity for biomass transformations George F. Tierney , Daniel Banks , Marina Carravetta , Alice E. Oakley , Shahram Alijani , Ilaria Barlocco , Nikolaos Dimitratos , Alberto Villa , Peter P. P. Wells Chemcatchem DOI: 10.1002/cctc.202401892 Diamond Proposal Number(s): [19850] Show Abstract ▼ Abstract: It is well-established that tailoring the structural properties of nanoparticles, e.g., their size, shape, available active surface and interaction with metal oxide supports, imparts significant control on catalytic transformations. However, this often relies on the use of stabilizing (capping) agents. These capping agents, predominantly long chain or bulky polymers, are not benign and also influence the catalytic performance. In this study, we expand on the use of surfactant-controlled reaction pathways for the hydrogenation of furfural on Pd/TiO2. Furthermore, we demonstrate how solid-state NMR is able to study the surfactant-catalyst interaction and how these can be correlated to the selectivity profile for furfural hydrogenation.	Apr 2025

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