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Instruments / Technical Area	Publication Details	Published
I15-Extreme Conditions	Structure and magnetism of collapsed lanthanide elements M. I. Mcmahon , S. Finnegan , R. J. Husband , K. A. Munro , E. Plekhanov , N. Bonini , C. Weber , M. Hanfland , U. Schwarz , S. G. Macleod Physical Review B 100 DOI: 10.1103/PhysRevB.100.024107 Show Abstract ▼ Abstract: Using synchrotron x-ray diffraction, we show that the long-accepted monoclinic structure of the “collapsed” high-pressure phases reported in seven lanthanide elements [Nd, Tb, Gd, Dy, Ho, Er, and (probably) Tm] is incorrect. In Tb, Gd, Dy, Ho, Er, and Tm we show that the collapsed phases have a 16-atom orthorhombic structure ( o F 16 ) not previously seen in the elements, whereas in Nd we show that it has an eight-atom orthorhombic structure ( o F 8 ) previously reported in several actinide elements. o F 16 and o F 8 are members of a new family of layered elemental structures, the discovery of which reveals that the high-pressure structural systematics of the lanthanides, actinides, and group-III elements (Sc and Y) are much more related than previously imagined. Electronic structure calculations of Tb, combined with quantum many-body corrections, confirm the experimental observation, and calculate that the collapsed orthorhombic phase is a ferromagnet, nearly degenerate with an antiferromagnetic state between 60 and 80 GPa. We find that the magnetic properties of Tb survive to the highest pressures obtained in our experiments (110 GPa). Further calculations of the collapsed phases of Gd and Dy, again using the correct crystal structure, show the former to be a type-A antiferromagnet, whereas the latter is ferromagnetic.	Jul 2019
I15-Extreme Conditions	Phase diagram of calcium at high pressure and high temperature S. Anzellini , D. Errandonea , Simon Macleod , P. Botella , D. Daisenberger , J. M. De’ath , J. Gonzalez-platas , J. Ibáñez , M. I. Mcmahon , K. A. Munro , C. Popescu , J. Ruiz-fuertes , C. W. Wilson Physical Review Materials 2 DOI: 10.1103/PhysRevMaterials.2.083608 Diamond Proposal Number(s): [15864] Show Abstract ▼ Abstract: Resistively heated diamond-anvil cells have been used together with synchrotron x-ray diffraction to investigate the phase diagram of calcium up to 50 GPa and 800 K. The phase boundaries between the Ca-I (fcc), Ca-II (bcc), and Ca-III (simple cubic, sc) phases have been determined at these pressure-temperature conditions, and the ambient temperature equation of state has been generated. The equation of state parameters at ambient temperature have been determined from the experimental compression curve of the observed phases by using third-order Birch-Murnaghan and Vinet equations. A thermal equation of state was also determined for Ca-I and Ca-II by combining the room-temperature Birch-Murnaghan equation of state with a Berman-type thermal expansion model.	Aug 2018
I15-Extreme Conditions	One-dimensional chain melting in incommensurate potassium Emma Mcbride , Keith Munro , Graham Stinton , Rachel Husband , Richard Briggs , H P Liermann , Malcolm Mcmahon Physical Review B 91 (14) DOI: 10.1103/PhysRevB.91.144111 Diamond Proposal Number(s): [8258] Show Abstract ▼ Abstract: Between 19 and 54 GPa, potassium has a complex composite incommensurate host-guest structure which undergoes two intraphase transitions over this pressure range. The temperature dependence of these host-guest phases is further complicated by the onset of an order-disorder transition in their guest chains. Here, we report single-crystal, quasi-single-crystal, and powder synchrotron x-ray diffraction measurements of this order-disorder phenomenon in incommensurate potassium to 47 GPa and 750 K. The so-called chain melting transition is clearly visible over a 22 GPa pressure range, and there are significant changes in the slope of the phase boundary which divides the ordered and disordered phases, one of which results from the intraphase transitions in the guest structure.	Apr 2015
I15-Extreme Conditions	Incommensurate-to-incommensurate phase transition in Eu metal at high pressures R. J. Husband , I. Loa , K. A. Munro , E. E. Mcbride , S. R. Evans , H. P Liermann , M. I. Mcmahon Physical Review B 90 (21), 10-15 DOI: 10.1103/PhysRevB.90.214105 Show Abstract ▼ Abstract: High pressure x-ray powder-diffraction experiments were performed on europium metal up to about 70GPa. Above 38 GPa, europium transforms from the incommensurately modulated Eu-IV phase to a second phase with an incommensurately modulated crystal structure, Eu-V. This is a previously unseen incommensurately modulated to incommensurately modulated transition in the elements at high pressure. High-pressure high-temperature experiments were also performed up to 449 K in order to make an initial estimate of the positions of the phase boundaries of the incommensurate phases.	Dec 2014
I15-Extreme Conditions	The distorted-fcc phase of samarium Rachel Husband , Ingo Loa , Keith Munro , Malcolm Mcmahon Journal Of Physics: Conference Series 500 DOI: 10.1088/1742-6596/500/3/032009 Show Abstract ▼ Abstract: Angle-dispersive x-ray powder diffraction experiments were performed on samarium metal up to 50 GPa. We report that the high-pressure distorted-fcc phase has the same hR24 structure observed in praseodymium, but, unlike praseodymium, samarium does not undergo a transition to a second distorted-fcc phase. We also report a path-dependent transition to a new phase, the structure of which has not yet been determined, which occurs on annealing followed by pressure decrease.	May 2014

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