Show Abstract ▼

Abstract: Additive manufacturing (AM; 3D Printing), a process which creates a part layer-by-layer, has the potential to improve upon conventional lightweight mirror manufacturing techniques, including subtractive (milling), formative (casting) and fabricative (bonding) manufacturing. Increased mass reduction whilst maintaining mechanical performance can be achieved through the creation of intricate lattice geometries, which are impossible to manufacture conventionally. Further, part consolidation can be introduced to reduce the number of interfaces and thereby points of failure. AM design optimisation using computational tools has been extensively covered in existing literature. However, additional research, specifically evaluation of the optical surface, is required to qualify these results before these advantages can be realised. This paper outlines the development and metrology of an AM mirror for a CubeSat platform with a targeted mass reduction of 60% compared to an equivalent solid body. This project aims to incorporate recent developments in AM mirror design, with a focus on manufacture, testing and evaluation. This is achieved through a simplified design process of a Cassegrain telescope primary mirror mounted within a 3U CubeSat chassis. The mirror geometry is annular with an external diameter of 84 mm and an internal diameter of 32 mm; the optical prescription is flat for ease of manufacture. Prototypes were printed in AlSi10Mg, a low-cost aluminium alloy commonly used in metal additive manufacturing. They were then machined and single-point diamond turned to achieve a reflective surface. Both quantitative and qualitative evaluations of the optical surface were conducted to assess the effect of hot isostatic pressing (HIP) on the optical surface quality. The results indicated that HIP reduced surface porosity; however, it also increased surface roughness and, consequently, optical scatter.

Open Access

Show Abstract ▼

Abstract: Colloids present a challenge for nuclear decommissioning and disposal due to their potential to mobilise radionuclides. Waste retrieval and decommissioning of storage ponds for spent nuclear fuel and silos for radioactive waste at the Sellafield nuclear facility, UK, are high priorities. The particulates characterised here originate from facilities >60 years old and provide a unique opportunity to investigate the long-term fate of radionuclides in an aquatic, engineered storage environment. Radioactive effluents were obtained from a legacy pond and characterised using ultrafiltration, transmission electron microscopy (TEM) and actinide L3 edge X-ray absorption spectroscopy (XAS). TEM analysis showed discrete UO2-like nanoparticles, 5-10 nm in size, often co-associated with Mg-Al- and Fe-(oxyhydr)oxide colloidal phases. Uranium XAS indicated a mix of uranium oxidation states with EXAFS suggesting U(IV)-oxide nanoparticles and sorbed U(VI). Pu XANES identified Pu(IV) as the dominant oxidation state. Both U and Pu associates with large, Mg/Al- and Fe-(oxyhydr)oxide agglomerates highlights the potential for pseudo-colloid formation, explaining the basis of current particle filtration / abatement of technology. This study, which examines novel samples from a complex, highly radioactive facility using advanced techniques, provides a new understanding of radionuclide speciation and mobility in these environments and informs radioactive effluent treatment and disposal.

Show Abstract ▼

Abstract: Additive manufacture (AM) involves creating a part layer by layer and is a rapidly evolving manufacturing process. It has multiple strengths that apply to space-based optics, such as the ability to consolidate multiple parts into one, reducing the number of interfaces. The process also allows for greater mass reduction, making parts more cost-effective to launch, achieved by optimising the shape for intended use or creating intricate geometries like lattices. However, previous studies have highlighted issues associated with the AM process. For example, when trying to achieve high-precision optical surfaces on AM parts, the latticing on the underside of mirrors can provide insufficient support during machining, resulting in the quilting effect. This paper builds on previous work and explores such challenges further. This will be implemented by investigating ways to apply AM to a deployable mirror from a CubeSat project called A-DOT. The reflective surface has a spherical radius of curvature of 682 mm and approximate external dimensions of 106 x 83 mm. The aim is to produce two mirrors that will take full advantage of AM design benefits and account for the challenges in printing and machining a near-net shape. The designs will have reduced mass by using selected internal lattice designs and topologyoptimised connection points, resulting in two mirrors with mass reduction targets of 50% and 70%. Once printed in aluminium using laser powder bed fusion, the reflective surface will be created using single point diamond turning. Finally, an evaluation of the dimensional accuracy will be conducted, using interferometry, to quantify the performance of the reflective surface.

Open Access

Show Abstract ▼

Abstract: The past 60+ years of global nuclear activity has resulted a signifcant legacy of radioactive contaminated lands which have high economic costs associated with their remediation. Developing clean-up technologies that are environmentally friendly, economically viable and effective in the long-term is key, with in-situ remediation techniques as an important option. However, questions remain regarding the most favorable methods of remediation, and the long-term stability of any immobilised radionuclide(s). Here, we used sediment microcosms to assess the long-term (300 day) stability of immobilised U and Sr formed during anoxic microbial and chemical treatments, and assessed their stability during re-oxidation scenarios (with oxygen or nitrate additions, 100 days). We used six contrasting treatment approaches which resulted in 89 - >99%, and 65 – 95% removal efficiencies for U and Sr, respectively. These included two Zero Valent Iron (ZVI) based products (NANOFER 25S and Carbo-Iron); a slow-release electron donor (Metals Remediation Compound, MRC) to stimulate U(VI) bioreduction alongside a readily bioavailable electron donor control (lactate/acetate mix); electron donor (lactate/acetate) with elevated sulfate to stimulate metal and sulfate reduction; glycerol phosphate to promote both bioreduction of U(VI) and biomineralization of inorganic U/Sr phopshates; and finally a natural attenuation (no remediation agent added) control. X-ray Absorption Spectroscopy (XAS) revealed that whilst aqueous U was removed from solution via multiple mechanisms including sorption, reduction and incorporation, aqueous Sr was mostly removed via outer sphere complexation mechanisms. Re-oxidation with air led to increased U remobilisation (≤89%) compared to nitrate oxidation (≤73%), but neither oxygen or nitrate re-oxidation led to significant Sr remobilisation (≤38%), suggesting Sr speciation may be stable over extended timescales post remediation. Treatments amended with ZVI or glycerol phosphate not only removed the most U and Sr from solution (>99%) but they also retained the most U and Sr following re-oxidation (retaining ≥75% of the originally added U and Sr). XAS analyses suggests that enhanced immbilisation, as seen in the treatments amended with ZVI or glycerol phosphate, may be due to the U/Sr incorporation into mineral phases (i.e., iron oxyhydorxide and phospate pahses) This suggests that optimal (bio)remediation strategies should target both reduction and biomineralisation mechanisms to facilitate radionuclide-mineral incorporation, promoting longer-term stability.

Open Access

Show Abstract ▼

Abstract: Citrate is a key decontaminant used in the nuclear industry and here we explore its biogeochemical fate in the presence of Ni2+ and U(VI)O22+ under conditions relevant to low level radioactive waste (LLW) disposal. Anaerobic microcosm experiments were performed under nitrate- and sulfate-reducing conditions at between pH 9 and 10. Citrate (1 mM) was supplied as both an electron donor and a potential metal ion complexant. Incubation experiments with citrate, inoculated with nitrate- or sulfate-reducing microbial consortia, were challenged with three different concentrations of Ni: 0.01, 0.1 or 1 mM, or U: 0.005, 0.05, or 0.5 mM. The nitrate- and sulfate-reducing inocula were enriched from well characterised alkaline sediments obtained from high pH lime-workings. A multi-technique approach was adopted to characterise the aqueous geochemistry, solid phase mineralogy, and bacterial communities in each incubation system. In the 0.01 mM Ni systems citrate underwent full biodegradation under both nitrate and sulfate-reducing conditions in less than 15 days. In the sulfate-reducing experiments, 50% of the added 0.01 mM Ni(aq) was removed from solution and black solids formed; SEM and TEM analysis suggested that these were Ni-sulfides. For the higher Ni concentration incubations, no changes were observed in the nitrate-amended experiments. In the sulfate-amended experiments only citrate fermentation was observed, likely because elevated levels of Ni were toxic to nitrate- and sulfate-reducing bacteria in the inocula. Interestingly, although fermentative bacteria were key citrate degraders in the sulfate-amended experiments they did not dominate in the nitrate-amended experiments presumably due to competition from other microbes. In the U experiments, citrate degradation took place over 55 days in all systems except the 0.5 mM U/nitrate-amended incubations. In all U/sulfate-amended experiments, a dark-coloured precipitate formed and XAS analysis indicated that these solids contained reduced U(IV) with EXAFS suggesting that non-crystalline U(IV)–phosphate phases dominated. Microbial community analysis by 16S rRNA gene sequencing of endpoint samples identified fermenters and nitrate- and sulfate-reducing bacteria in the relevant incubations. Overall, findings suggest microbial degradation of citrate occurs under repository relevant conditions with Ni (at 0.01–0.1 mM) and U (at 0.005–0.5 mM) but with an inhibitory effect particularly at elevated Ni concentrations. Significantly, the work suggests that under anaerobic conditions relevant to LLW disposal, citrate undergoes biodegradation leading to the development of poorly soluble Ni sulfides and/or bioreduction of U(VI) to poorly soluble U(IV) phases. This suggests that both removal of citrate, and retention of Ni and U can occur in these environments and this information can be used to further inform development of safety cases for radioactive waste disposal.