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59 items found (0 items not approved), displaying 1 to 10.[First/Prev] 1, 2, 3, 4, 5, 6 [Next/Last]

Instruments / Technical Area	Publication Details	Published
I15-Extreme Conditions	Grguricite, CaCr2(CO3)2(OH)4.4H2O, a new alumohydrocalcite analogue M. S. Rumsey , M. D. Welch , J. Spratt , A. K. Kleppe Mineralogical Magazine DOI: 10.1180/mgm.2020.66 Show Abstract ▼ Abstract: The occurrence and characterization of a new member of the dundasite group are reported. Grguricite, ideally CaCr2(CO3)2(OH)4·4H2O, is the Cr-analogue of alumohydrocalcite, CaAl2(CO3)2(OH)4·4H2O and occurs as lilac crusts of very fine-grained crystalline aggregates in the Pb-Ba-V mineralization found at the Adeghoual Mine, Mibladen, Morocco (32°46′0′′ N, 4°37′59′′ W). The identification was based upon a close match with the X-ray powder diffraction data for alumohydrocalcite, the confirmation of anion components identified by Raman spectroscopy and the cation composition determined by electron-probe microanalysis. The empirical formula based upon 14 oxygen atoms per formula unit is Ca0.84Pb0.03Cr1.65Al0.39Mg0.02(CO3)2(OH)4·4H2O, with carbonate, hydroxyl and water contents set to those of the alumohydrocalcite stoichiometry. The fine-grained nature of the crystals (c. 0.5 x 0.1 x 5 μm) precluded a single-crystal X-ray study and both density and optical determinations. Grguricite is triclinic with space group P1 ̄. Unit-cell parameters refined from the powder diffraction data are: a = 5.724(2) Å, b = 6.5304(9) Å, c = 14.646(4) Å, α = 81.682(1)°, β = 83.712(2)°, γ = 86.365(2)°, V = 537.8(2) Å3, Z = 2. The five strongest peaks in the powder pattern are [dhkl , I/Imax, (hkl)]: [6.222, 100, (011)], [3.227, 87, (020)], [6.454, 63, (010)], [2.883, 58, (005, 023, 121)], [7.208, 45, (002)]. The mineral is named after Australian geologist Ben Grguric.	Sep 2020
I15-Extreme Conditions	Mechanism of enhanced energy storage in AgNbO3-based lead-free antiferroelectrics Zhilun Lu , Weichao Bao , Ge Wang , Shikuan Sun , Linhao Li , Jinglei Li , Huijing Yang , Hongfen Ji , Antonio Feteira , Dejun Li , Fangfang Xu , Annette K. Kleppe , Dawei Wang , Shi-yu Liu , Ian M. Reaney Nano Energy DOI: 10.1016/j.nanoen.2020.105423 Diamond Proposal Number(s): [21714] Open Access Show Abstract ▼ Abstract: The mechanisms underpinning high energy storage in lead-free Ag1-3xNdxTayNb1-yO3 antiferroelectric (AFE) ceramics have been investigated. Rietveld refinements of in-situ synchrotron X-ray data reveal that the structure remains quadrupled and orthorhombic under electric field (E) but adopts a non-centrosymmetric space group, Pmc21, in which the cations exhibit a ferrielectric configuration. Nd and Ta doping both stabilise the AFE structure, thereby increasing the AFE-ferrielectric switching field from 150 to 350 kV cm-1. Domain size and correlation length of AFE/ferrielectric coupling reduce with Nd doping, leading to slimmer hysteresis loops. Pmax is optimised through A-site aliovalent doping which also decreases electrical conductivity, permitting the application of a larger E. These effects combine to enhance energy storage density to give Wrec = 6.5 J cm-3 for Ag0.97Nd0.01Ta0.20Nb0.80O3.	Sep 2020
I15-Extreme Conditions	Mechanical behavior and phase change of alkali-silica reaction products under hydrostatic compression Guoqing Geng , Zhenguo Shi , Andreas Leemann , Konstantin Glazyrin , Annette Kleppe , Dominik Daisenberger , Sergey Churakov , Barbara Lothenbach , Erich Wieland , Rainer Daehn Acta Crystallographica Section B Structural Science, Crystal Engineering And Materials 76, 674 - 682 DOI: 10.1107/S205252062000846X Diamond Proposal Number(s): [18643] Show Abstract ▼ Abstract: Alkali-silica reaction (ASR) causes severe degradation of concrete. The mechanical property of the ASR product is fundamental to the multiscale modeling of concrete behavior over the long term. Despite years of study, there is a lack of consensus regarding the structure and elastic modulus of the ASR product. Here, ASR products from both degraded field infrastructures and laboratory synthesis were investigated using high-pressure X-ray diffraction. The results unveiled the multiphase and metastable nature of ASR products from the field. The dominant phase undergoes permanent phase change via collapsing of the interlayer region and in-planar glide of the main layer, under pressure >2 GPa. The bulk moduli of the low- and high-pressure polymorphs are 27±3 and 46±3 GPa, respectively. The laboratory-synthesized sample and the minor phase in the field samples undergo no changes of phase during compression. Their bulk moduli are 35±2 and 76±4 GPa, respectively. The results provide the first atomistic-scale measurement of the mechanical property of crystalline ASR products.	Aug 2020
I15-Extreme Conditions	Structural ordering in liquid gallium under extreme conditions James W. E. Drewitt , Francesco Turci , Benedict J. Heinen , Simon G. Macleod , Fei Qin , Annette K. Kleppe , Oliver T. Lord Physical Review Letters 124 DOI: 10.1103/PhysRevLett.124.145501 Diamond Proposal Number(s): [18961] Open Access Show Abstract ▼ Abstract: The atomic-scale structure, melting curve, and equation of state of liquid gallium has been measured to high pressure ( p ) and high temperature ( T ) up to 26 GPa and 900 K by in situ synchrotron x-ray diffraction. Ab initio molecular dynamics simulations up to 33.4 GPa and 1000 K are in excellent agreement with the experimental measurements, providing detailed insight at the level of pair distribution functions. The results reveal an absence of dimeric bonding in the liquid state and a continuous increase in average coordination number ¯ n Ga Ga from 10.4(2) at 0.1 GPa approaching ∼ 12 by 25 GPa. Topological cluster analysis of the simulation trajectories finds increasing fractions of fivefold symmetric and crystalline motifs at high p − T . Although the liquid progressively resembles a hard-sphere structure towards the melting curve, the deviation from this simple description remains large ( ≥ 40 % ) across all p − T space, with specific motifs of different geometries strongly correlating with low local two-body excess entropy at high p − T .	Apr 2020
I15-Extreme Conditions	Quasi-hydrostatic equation of state of silicon up to 1 megabar at ambient temperature Simone Anzellini , Michael T. Wharmby , Francesca Miozzi , Annette Kleppe , Dominik Daisenberger , Heribert Wilhelm Scientific Reports 9 DOI: 10.1038/s41598-019-51931-1 Diamond Proposal Number(s): [13527] Open Access Show Abstract ▼ Abstract: The isothermal equation of state of silicon has been determined by synchrotron x-ray diffraction experiments up to 105.2 GPa at room temperature using diamond anvil cells. A He-pressure medium was used to minimize the effect of uniaxial stress on the sample volume and ruby, gold and tungsten pressure gauges were used. Seven different phases of silicon have been observed along the experimental conditions covered in the present study.	Oct 2019
I15-Extreme Conditions	Origin of the large electrostrain in BiFeO 3 -BaTiO 3 based lead-free ceramics Ge Wang , Zhongming Fan , Shunsuke Murakami , Zhilun Lu , David A. Hall , Derek C. Sinclair , Antonio Feteira , Xiaoli Tan , Jacob L. Jones , Annette K. Kleppe , Dawei Wang , Ian M. Reaney Journal Of Materials Chemistry A 21 DOI: 10.1039/C9TA07904A Diamond Proposal Number(s): [19590] Show Abstract ▼ Abstract: High electrostrain and breakdown strength (1 − x)BiFeO3-0.3BaTiO3-xNd(Li0.5Nb0.5)O3 (BF-BT-xNLN) ceramics were studied by in situ synchrotron X-ray diffraction (XRD) in combination with Rietveld refinement and conventional transmission electron microscopy. At zero field, compositions transformed from majority ferroelectric rhombohedral to pseudocubic as the NLN concentration increased, with 0.27% strain achieved at 60 kV cm−1 for x = 0.01. The large measured macroscopic strain was commensurate with peak shifting in XRD peak profiles, yielding 0.6% total strain at 150 kV cm−1. Strain anisotropy of ε200 > ε220 > ε111 was observed but despite the large applied field, no peak splitting was detected. We therefore concluded that the large electrostrain is not achieved through a conventional relaxor to field induced long-range ferroelectric transition. Instead, the data supports a model where local polar regions distort in the direction of the applied field within multiple local symmetries (pseudosymmetry) without long range correlation. We proposed that pseudosymmetry is maintained in BF-BT-xNLN even at high field (150 kV cm−1) due to the large ion radii mismatch and competing ionic/covalent bonding between Ba2+ and Bi3+ ions.	Aug 2019
I15-Extreme Conditions	The effect of pressure and composition on Cu-bearing hydroxide perovskite Jens Najorka , Annette K. Kleppe , Mark D. Welch Physics And Chemistry Of Minerals 36 DOI: 10.1007/s00269-019-01047-9 Diamond Proposal Number(s): [9903, 11121] Open Access Show Abstract ▼ Abstract: Hydroxide perovskite solid solutions along the CuxZn1−xSn(OH)6 join have been investigated at ambient conditions. Two compositions, Cu0.4Zn0.6Sn(OH)6 (cubic) and CuSn(OH)6 (tetragonal), have also been studied at pressures up to 17 GPa. In both ambient and high-pressure experiments, samples were characterised using powder X-ray diffraction. Bulk compositions between 0 ≤ XCu ≤ 0.4 are metrically cubic (space group Pn 3 ¯ 3¯ ), whereas those with XCu = 0.9 and 1 produced single-phase tetragonal Cu0.9Zn0.1Sn(OH)6 and CuSn(OH)6 (space group P42/n). The products of syntheses with 0.5 ≤ XCu ≤ 0.8 contain coexisting cubic and tetragonal phases. The cubic → tetragonal transformation is rationalised in terms of being driven by local strain associated with the accumulation of Cu-rich domains in the cubic phase. The high-pressure studies of cubic Cu0.4Zn0.6Sn(OH)6 and tetragonal CuSn(OH)6 phases showed contrasting behaviour. The compression curve of the cubic phase is smooth without inflexion or discontinuity to 17 GPa. The derived bulk modulus of Cu0.4Zn0.6Sn(OH)6 is K0 = 75.8(4) GPa (K′ = 4). For CuSn(OH)6, compression data cannot be fitted by a single equation-of-state over the entire pressure range to 17 GPa, as there is a clear discontinuity between 7 and 10 GPa that corresponds to an increase in compressibility at higher pressures. Compression data for CuSn(OH)6 to 7 GPa are: K0 = 59.7(9) GPa, Ka0 = 79(2) GPa, and Kc0 = 38.0(3) GPa (K′ = 4 for all). It is shown that the strong Jahn–Teller distortion associated with the Cu(OH)6 octahedron is primarily responsible for the discontinuous and highly anisotropic compressional behaviour of the unit cell of CuSn(OH)6 hydroxide perovskite.	Jul 2019
I15-Extreme Conditions	Quenching-assisted actuation mechanisms in core-shell structured BiFeO3−BaTiO3 piezoceramics Ilkan Calisir , Annette K. Kleppe , Antonio Feteira , David A. Hall Journal Of Materials Chemistry C DOI: 10.1039/C9TC01583C Diamond Proposal Number(s): [16390] Show Abstract ▼ Abstract: Electromechanical actuation in piezoceramics is usually enhanced by creating chemically homogeneous materials with structurally heterogeneous morphotropic phase boundaries, leading to abrupt changes in ion displacement directions within the perovskite unit cell. In the present study, an alternative mechanism to enhance electromechanical coupling is found in both chemically and structurally heterogeneous BiFeO3−BaTiO3 lead-free piezoceramics. Such a mechanism is observed in a composition exhibiting core-shell type microstructure, associated with donor-type substitution of Ti4+ for Fe3+, and is primarily activated by thermal quenching treatment. Here, we describe the use of in-situ high-energy synchrotron X-ray powder diffraction upon the application of a high electric field to directly monitor the ferroelectric and elastic interactions between these composite-like components, formed as core and shell regions within grains. Translational short or long-range ordering is observed in the BiFeO3‒depleted shell regions which undergo significant structural alterations from pseudocubic Pm-3m relaxor-ferroelectric in slow-cooled ceramics to rhombohedral R3c or R3m with long-range ferroelectric order in the quenched state. The strain contributions from each component are calculated, leading to the conclusion that the total macroscopic strain arises predominantly from the transformed shell after quenching. Such observations are also complemented by investigations of microstructure and electrical properties, including ferroelectric behaviour and temperature-dependent dielectric properties.	Jul 2019
I15-Extreme Conditions	Rich polymorphism of a metal-organic framework in pressure-temperature space Remo N. Widmer , Giulio I. Lampronti , Siwar Chibani , Craig Wilson , Simone Anzellini , Stefan Farsang , Annette K. Kleppe , Nicola P. M. Casati , Simon Macleod , Simon A. T. Redfern , François-xavier Coudert , Thomas D. Bennett Journal Of The American Chemical Society DOI: 10.1021/jacs.9b03234 Diamond Proposal Number(s): [19046] Show Abstract ▼ Abstract: We present an in-situ powder X-ray diffraction study on the phase stability and polymorphism of the metal-organic framework ZIF-4, Zn(Imidazolate)2, at simultaneous high-pressure and high-temperature, up to 8 GPa and 600 °C. The resulting pressure-temperature phase diagram reveals four, previously unknown, high-pressure-temperature ZIF phases. The crystal structures of two new phases – ZIF-4-cp-II and ZIF-hPT-II – were solved by powder diffraction methods. The total energy of ZIF-4-cp-II was evaluated using density functional theory calculations and was found to lie in between that of ZIF-4 and the most thermodynamically stable polymorph, ZIF-zni. ZIF-hPT-II was found to possess a doubly-interpenetrated diamondoid-topology and is isostructural with previously reported Cd(Imidazolate)2 and Hg(Imidazolate)2 phases. This phase exhibited extreme resistance to both temperature and pressure. The other two new phases could be assigned with a unit cell and space group, though their structures remain unknown. The pressure-temperature phase diagram of ZIF-4 is strikingly complicated when compared with that of the previously investigated, closely related ZIF-62, and demonstrates the ability to traverse complex energy landscapes of metal-organic systems using the combined application of pressure and temperature.	May 2019
I15-Extreme Conditions	The fate of carbonate in oceanic crust subducted into earth's lower mantle James W. E. Drewitt , Michael J. Walter , Hongluo Zhang , Sorcha C. Mcmahon , David Edwards , Benedict J. Heinen , Oliver T. Lord , Simone Anzellini , Annette K. Kleppe Earth And Planetary Science Letters 511, 213 - 222 DOI: 10.1016/j.epsl.2019.01.041 Diamond Proposal Number(s): [10617, 11896, 15288, 17994] Open Access Show Abstract ▼ Abstract: We report on laser-heated diamond anvil cell (LHDAC) experiments in the FeO–MgO–SiO2–CO2 (FMSC) and CaO–MgO–SiO2–CO2 (CMSC) systems at lower mantle pressures designed to test for decarbonation and diamond forming reactions. Sub-solidus phase relations based on synthesis experiments are reported in the pressure range of ∼35 to 90 GPa at temperatures of ∼1600 to 2200 K. Ternary bulk compositions comprised of mixtures of carbonate and silica are constructed such that decarbonation reactions produce non-ternary phases (e.g. bridgmanite, Ca-perovskite, diamond, CO2–V), and synchrotron X-ray diffraction and micro-Raman spectroscopy are used to identify the appearance of reaction products. We find that carbonate phases in these two systems react with silica to form bridgmanite ±Ca-perovskite + CO2 at pressures in the range of ∼40 to 70 GPa and 1600 to 1900 K in decarbonation reactions with negative Clapeyron slopes. Our results show that decarbonation reactions form an impenetrable barrier to subduction of carbonate in oceanic crust to depths in the mantle greater than ∼1500 km. We also identify carbonate and CO2–V dissociation reactions that form diamond plus oxygen. On the basis of the observed decarbonation reactions we predict that the ultimate fate of carbonate in oceanic crust subducted into the deep lower mantle is in the form of refractory diamond in the deepest lower mantle along a slab geotherm and throughout the lower mantle along a mantle geotherm. Diamond produced in oceanic crust by subsolidus decarbonation is refractory and immobile and can be stored at the base of the mantle over long timescales, potentially returning to the surface in OIB magmas associated with deep mantle plumes.	Apr 2019

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