I09-Surface and Interface Structural Analysis
|
Zachary W.
Lebens-higgins
,
Hyeseung
Chung
,
Mateusz J.
Zuba
,
Jatinkumar
Rana
,
Yixuan
Li
,
Nicholas V.
Faenza
,
Nathalie
Pereira
,
Bryan D.
Mccloskey
,
Fanny
Rodolakis
,
Wanli
Yang
,
M. Stanley
Whittingham
,
Glenn G.
Amatucci
,
Ying Shirley
Meng
,
Tien-lin
Lee
,
Louis F. J.
Piper
Diamond Proposal Number(s):
[22250, 22148]
Abstract: Sensitivity to the `bulk' oxygen core orbital makes hard X-ray photoelectron spectroscopy (HAXPES) an appealing technique for studying oxygen redox candidates. Various studies have reported an additional O 1s peak (530-531 eV) at high voltages, which has been considered a direct signature of the bulk oxygen redox process. Here, we find the emergence of a 530.4 eV O 1s HAXPES peak for three model cathodes, Li2MnO3, Li-rich NMC, and NMC 442, that shows no clear link to expected oxygen redox. Instead, the 530.4 eV peak for these three systems is attributed to transition metal reduction and electrolyte decomposition in the near-surface region. Claims of oxygen redox relying on photoelectron spectroscopy must explicitly account for the surface sensitivity of this technique and the extent of the cathode degradation layer.
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Feb 2020
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I09-Surface and Interface Structural Analysis
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Jatinkumar
Rana
,
Joseph K.
Papp
,
Zachary
Lebens-higgins
,
Mateusz
Zuba
,
Lori A.
Kaufman
,
Anshika
Goel
,
Richard
Schmuch
,
Martin
Winter
,
M. Stanley
Whittingham
,
Wanli
Yang
,
Bryan D.
Mccloskey
,
Louis F. J.
Piper
Diamond Proposal Number(s):
[22250]
Abstract: Though Li2MnO3 was originally considered to be electrochemically inert, its observed activation has spawned a new class of Li-rich layered compounds that deliver capacities beyond the traditional transition-metal redox limit. Despite progress in our understanding of oxygen redox in Li-rich compounds, the underlying origin of the initial charge capacity of Li2MnO3 remains hotly contested. To resolve this issue, we review all possible charge compensation mechanisms including bulk oxygen redox, oxidation of Mn4+, and surface degradation for Li2MnO3 cathodes displaying capacities exceeding 350 mAh g–1. Using elemental and orbital selective X-ray spectroscopy techniques, we rule out oxidation of Mn4+ and bulk oxygen redox during activation of Li2MnO3. Quantitative gas-evolution and titration studies reveal that O2 and CO2 release accounted for a large fraction of the observed capacity during activation with minor contributions from reduced Mn species on the surface. These studies reveal that, although Li2MnO3 is considered critical for promoting bulk anionic redox in Li-rich layered oxides, Li2MnO3 by itself does not exhibit bulk oxygen redox or manganese oxidation beyond its initial Mn4+ valence.
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Jan 2020
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I09-Surface and Interface Structural Analysis
|
Zachary W.
Lebens-higgins
,
David M.
Halat
,
Nicholas V.
Faenza
,
Matthew J.
Wahila
,
Manfred
Mascheck
,
Tomas
Wiell
,
Susanna K.
Eriksson
,
Paul
Palmgren
,
Jose
Rodriguez
,
Fadwa
Badway
,
Nathalie
Pereira
,
Glenn G.
Amatucci
,
Tien-lin
Lee
,
Clare P.
Grey
,
Louis F. J.
Piper
Diamond Proposal Number(s):
[22250, 22148]
Open Access
Abstract: Aluminum is a common dopant across oxide cathodes for improving the bulk and cathode-electrolyte interface (CEI) stability. Aluminum in the bulk is known to enhance structural and thermal stability, yet the exact influence of aluminum at the CEI remains unclear. To address this, we utilized a combination of X-ray photoelectron and absorption spectroscopy to identify aluminum surface environments and extent of transition metal reduction for Ni-rich LiNi0.8Co0.2−yAlyO2 (0%, 5%, or 20% Al) layered oxide cathodes tested at 4.75 V under thermal stress (60 °C). For these tests, we compared the conventional LiPF6 salt with the more thermally stable LiBF4 salt. The CEI layers are inherently different between these two electrolyte salts, particularly for the highest level of Al-doping (20%) where a thicker (thinner) CEI layer is found for LiPF6 (LiBF4). Focusing on the aluminum environment, we reveal the type of surface aluminum species are dependent on the electrolyte salt, as Al-O-F- and Al-F-like species form when using LiPF6 and LiBF4, respectively. In both cases, we find cathode-electrolyte reactions drive the formation of a protective Al-F-like barrier at the CEI in Al-doped oxide cathodes.
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Dec 2019
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I09-Surface and Interface Structural Analysis
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Jack E. N.
Swallow
,
Benjamin A. D.
Williamson
,
Sanjayan
Sathasivam
,
Max
Birkett
,
Thomas J.
Featherstone
,
Philip A. E.
Murgatroyd
,
Holly J.
Edwards
,
Zachary W.
Lebens-higgins
,
David A.
Duncan
,
Mark
Farnworth
,
Paul
Warren
,
Nianhua
Peng
,
Tien-lin
Lee
,
Louis F. J.
Piper
,
Anna
Regoutz
,
Claire J.
Carmalt
,
Ivan P.
Parkin
,
Vin R.
Dhanak
,
David O.
Scanlon
,
Tim D.
Veal
Diamond Proposal Number(s):
[18428]
Open Access
Abstract: Transparent conductors are a vital component of smartphones, touch-enabled displays, low emissivity windows and thin film photovoltaics. Tin-doped In2O3 (ITO) dominates the transparent conductive films market, accounting for the majority of the current multi-billion dollar annual global sales. Due to the high cost of indium, however, alternatives to ITO have been sought but have inferior properties. Here we demonstrate that molybdenum-doped In2O3 (IMO) has higher mobility and therefore higher conductivity than ITO with the same carrier density. This also results in IMO having increased infrared transparency compared to ITO of the same conductivity. These properties enable current performance to be achieved using thinner films, reducing the amount of indium required and raw material costs by half. The enhanced doping behavior arises from Mo 4d donor states being resonant high in the conduction band and negligibly perturbing the host conduction band minimum, in contrast to the adverse perturbation caused by Sn 5s dopant states. This new understanding will enable better and cheaper TCOs based on both In2O3 and other metal oxides.
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Sep 2019
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I09-Surface and Interface Structural Analysis
|
Diamond Proposal Number(s):
[16005]
Abstract: Zn
M
I
I
I
2
O
4
(
M
I
I
I
=
Co
, Rh, Ir) spinels have been recently identified as promising
p
-type semiconductors for transparent electronics. However, discrepancies exist in the literature regarding their fundamental optoelectronic properties. In this paper, the electronic structures of these spinels are directly investigated using soft/hard x-ray photoelectron and x-ray absorption spectroscopies in conjunction with density functional theory calculations. In contrast to previous results,
ZnCo
2
O
4
is found to have a small electronic band gap with forbidden optical transitions between the true band edges, allowing for both bipolar doping and high optical transparency. Furthermore, increased
d
−
d
splitting combined with a concomitant lowering of Zn
s
/
p
conduction states is found to result in a
ZnCo
2
O
4
(
ZCO
)
<
ZnRh
2
O
4
(
ZRO
)
≈
ZnIr
2
O
4
(
ZIO
)
band gap trend, finally resolving long-standing discrepancies in the literature.
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Aug 2019
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I09-Surface and Interface Structural Analysis
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Zachary W.
Lebens-higgins
,
Nicholas V.
Faenza
,
Maxwell D.
Radin
,
Hao
Liu
,
Shawn
Sallis
,
Jatinkumar
Rana
,
Julija
Vinckeviciute
,
Philip J.
Reeves
,
Mateusz
Zuba
,
Fadwa
Badway
,
Nathalie
Pereira
,
Karena W.
Chapman
,
Tien-lin
Lee
,
Tianpin
Wu
,
Clare P.
Grey
,
Brent
Melot
,
Anton
Van Der Ven
,
Glenn G.
Amatucci
,
Wanli
Yang
,
Louis F. J.
Piper
Diamond Proposal Number(s):
[19162]
Open Access
Abstract: Oxygen participation, arising from increased transition metal–oxygen covalency during delithiation, is considered essential for the description of charge compensation in conventional layered oxides. The advent of high-resolution mapping of the O K-edge resonant inelastic X-ray scattering (RIXS) provides an opportunity to revisit the onset and extent of oxygen participation. Combining RIXS with an array of structural and electronic probes for the family of Ni-rich LiNi0.8Co0.2−yAlyO2 cathodes, we identify common charge compensation regimes that are assigned to formal transition metal redox (<4.25 V) and oxygen participation through covalency (>4.25 V). From O K-edge RIXS maps, we find the emergence of a sharp RIXS feature in these systems when approaching full delithiation, which has previously been associated with lattice oxidized oxygen in alkali-rich systems. The lack of transition metal redox signatures and strong covalency at these high degrees of delithiation suggest this RIXS feature is similarly attributed to lattice oxygen charge compensation as in the alkali-rich systems. The RIXS feature's evolution with state of charge in conventional layered oxides is evidence that this feature reflects the depopulation of occupied O 2p states associated with oxygen participation.
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Jul 2019
|
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I09-Surface and Interface Structural Analysis
|
Zachary W.
Lebens-higgins
,
Shawn
Sallis
,
Nicholas V.
Faenza
,
Fadwa
Badway
,
Nathalie
Pereira
,
David M.
Halat
,
Matthew
Wahila
,
Christoph
Schlueter
,
Tien-lin
Lee
,
Wanli
Yang
,
Clare P.
Grey
,
Glenn G.
Amatucci
,
Louis F. J.
Piper
Diamond Proposal Number(s):
[12764, 16005]
Abstract: For layered oxide cathodes, impedance growth and capacity fade related to reactions at the cathode-electrolyte interface (CEI) are particularly prevalent at high voltage and high temperatures. At a minimum, the CEI layer consists of Li2CO3, LiF, reduced (relative to the bulk) metal-ion species, and salt decomposition species but conflicting reports exist regarding their progression during (dis)charging. Utilizing transport measurements in combination with x-ray and nuclear magnetic resonance spectroscopy techniques, we study the evolution of these CEI species as a function of electrochemical and thermal stress for LiNi0.8Co0.15Al0.05O2 (NCA) particle electrodes using a LiPF6 ethylene carbonate: dimethyl carbonate (1:1 volume ratio) electrolyte. Although initial surface metal reduction does correlate with surface Li2CO3 and LiF, these species are found to decompose upon charging and are absent above 4.25 V. While there is trace LiPF6 breakdown at room temperature above 4.25 V, thermal aggravation is found to strongly promote salt breakdown and contributes to surface degradation even at lower voltages (4.1 V). An interesting finding of our work was the partial reformation of LiF upon discharge which warrants further consideration for understanding CEI stability during cycling.
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Jan 2018
|
|
I09-Surface and Interface Structural Analysis
|
Zachary W.
Lebens-higgins
,
Nicholas
Faenza
,
Pinaki
Mukherjee
,
Shawn
Sallis
,
Fadwa
Badway
,
Nathalie
Pereira
,
Christoph
Schlueter
,
Tien-lin
Lee
,
Frederic
Cosandey
,
Glenn
Amatucci
,
Louis F. J.
Piper
Abstract: For layered oxide cathodes, aluminum doping has widely been shown to improve performance, particularly at high degrees of delithiation. While this has led to increased interest in Al-doped systems, including LiNi0.8Co0.15Al0.05O2 (NCA), the aluminum surface environment has not been thoroughly investigated. Using hard x-ray photoelectron spectroscopy measurements of the Al 1s core region for NCA electrodes, we examined the evolution of the surface aluminum environment under electrochemical and thermal stress. By correlating the aluminum environment to transition metal reduction and electrolyte decomposition, we provide further insight into the cathode-electrolyte interface layer. A remarkable finding is that Al-O coatings in LiPF6 electrolyte mimic the evolution observed for the aluminum surface environment in doped layered oxides.
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Dec 2017
|
|
I09-Surface and Interface Structural Analysis
|
Diamond Proposal Number(s):
[12764, 16005]
Abstract: Through operando synchrotron powder X-ray diffraction (XRD) analysis of layered transition metal oxide electrodes of composition LiNi0.8Co0.15Al0.05O2 (NCA), we decouple the intrinsic bulk reaction mechanism from surface-induced effects. For identically prepared and cycled electrodes stored in different environments, we demonstrate that the intrinsic bulk reaction for pristine NCA follows solid-solution mechanism, not a two-phase as suggested previously. By combining high resolution powder X-ray diffraction, diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) and surface sensitive X-ray photoelectron spectroscopy (XPS), we demonstrate that adventitious Li2CO3 forms on the electrode particle surface during exposure to air, through reaction with atmospheric CO2. This surface impedes ionic and electronic transport to the underlying electrode, with progressive erosion of this layer during cycling giving rise to different reaction states in particles with an intact vs an eroded Li2CO3 surface-coating. This reaction heterogeneity, with a bimodal distribution of reaction states, has previously been interpreted as a “two-phase” reaction mechanism for NCA, as an activation step that only occurs during the first cycle. Similar surface layers may impact the reaction mechanism observed in other electrode materials using bulk probes such as operando powder XRD.
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Aug 2017
|
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I09-Surface and Interface Structural Analysis
|
Nicholas V.
Faenza
,
Zachary W.
Lebens-higgins
,
Pinaki
Mukherjee
,
Shawn
Sallis
,
Nathalie
Pereira
,
Fadwa
Badway
,
Anna
Halajko
,
Gerbrand
Ceder
,
Frederic
Cosandey
,
Louis F. J.
Piper
,
Glenn G.
Amatucci
Diamond Proposal Number(s):
[12764]
Abstract: Enabling practical utilization of layered R-3m positive electrodes near full delithiation requires an enhanced understanding of the complex electrode-electrolyte interactions that often induce failure. Using Li[Ni0.8Co0.15Al0.05]O2 (NCA) as a model layered compound, the chemical and structural stability in a strenuous thermal and electrochemical environment was explored. Operando microcalorimetry and electrochemical impedance spectroscopy identified a fingerprint for a structural decomposition and transition metal dissolution reaction that occurs on the positive electrode at full delithiation. Surface sensitive characterization techniques, including X-ray absorption spectroscopy and high resolution transmission electron microscopy, measured a structural and morphological transformation of the surface and subsurface regions of NCA. Despite the bulk structural integrity being maintained, NCA surface degradation at a high state of charge induces excessive transition metal dissolution and significant positive electrode impedance development, resulting in a rapid decrease of electrochemical performance. Additionally, the impact of electrolyte salt, positive electrode surface area, and surface Li2CO3 content on the magnitude and character of the dissolution reaction was studied.
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Jun 2017
|
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