Search Results

You searched for all publications:

with publication states 'Published' 'Published (Approved)'

Search Again...

These results include publications that have not yet been reviewed and processed by Diamond Light Source. To view only processed publications click here.

You can use the folder icon under Actions to collate papers as required. You can then click on View Folder in the left-hand navigation to review and/or download your folder.

Exact matches
Related results

2 items found (0 items not approved), displaying all items.1

Instruments / Technical Area	Publication Details	Published	Actions
I19-Small Molecule Single Crystal Diffraction	Layered Zn2[Co(CN)6](CH3COO) double metal cyanide: a two-dimensional DMC phase with excellent catalytic performance Carlos Marquez , Arkadiy Simonov , Michael Wharmby , Cédric Van Goethem , Ivo Vankelecom , Bart Bueken , Andraž Krajnc , Gregor Mali , Dirk De Vos , Trees De Baerdemaeker Chemical Science 10, 4868-4875 DOI: 10.1039/C9SC00527G Diamond Proposal Number(s): [13639] Open Access Show Abstract ▼ Abstract: Double metal cyanides (DMCs) are well known, industrially applied catalysts for ring opening polymerization reactions. In recent years, they have been studied for a variety of catalytic reactions, as well as other applications, such as energy storage and Cs sorption. Herein, a new, layered DMC phase (L-DMC), Zn2[Co(CN)6](CH3COO)·4H2O, was synthesized. The structure, which crystallizes in the monoclinic space group P21/m, consists of positively charged {Zn2Co(CN)6}+ DMC layers linked through acetate groups and presents a new layered structure to the family of double metal cyanides. L-DMC proved to be a reusable and stable catalyst that exhibited a higher activity than the benchmark DMC catalyst in two important applications: hydroamination of phenylacetylene with 4-isopropylaniline and polymerization of 1,2-epoxyhexane.	Apr 2019
I11-High Resolution Powder Diffraction	Tunable Prussian blue analogues for the selective synthesis of propargylamines through A 3 coupling Carlos Marquez , Francisco G. Cirujano , Cédric Van Goethem , Ivo Vankelecom , Dirk De Vos , Trees De Baerdemaeker Catalysis Science & Technology 125 DOI: 10.1039/C8CY00073E Diamond Proposal Number(s): [13284] Open Access Show Abstract ▼ Abstract: M1[Co(CN)6]2/3-type Prussian blue analogues (M1–Co PBAs) were studied as catalysts for the synthesis of propargylamines via A3 coupling of phenylacetylene, benzaldehyde and piperidine. Cu0.86Zn0.14–Co PBA was the best catalyst for the reaction by combining the high conversion obtained with Cu–Co PBA with the excellent selectivity obtained with Zn–Co PBA.	Mar 2018

Publications Database

Search Results

You searched for all publications:

Search Again...

Subject Areas (check all that apply) select all

Instruments used to collect data (check all that apply) select all

Collaborations involved (check all that apply) select all

Diamond Offline Facilities used

Relevant Technical Areas (check all that apply) select all

Menu for Anonymous User