Diamond Publications - Search Results

Search Again...

These results include publications that have not yet been reviewed and processed by Diamond Light Source. To view only processed publications click here.

You can use the folder icon under Actions to collate papers as required. You can then click on View Folder in the left-hand navigation to review and/or download your folder.

One item found (0 items not approved).

Instruments / Technical Area	Publication Details	Published	Actions
I22-Small angle scattering & Diffraction	Core-shell spheroidal hydrogels produced via charge-driven interfacial complexation Vincenzo Calabrese , Davide Califano , Marcelo A. Da Silva , Julien Schmitt , Saffron J. Bryant , Kazi M. Zakir Hossain , Ana Maria Percebom , Aurora Perez-Gramatges , Janet Lesley Scott , Karen J. Edler Acs Applied Polymer Materials DOI: 10.1021/acsapm.9b01086 Diamond Proposal Number(s): [20409] Open Access Show Abstract ▼ Abstract: Through charge-driven interfacial complexation, we produced millimetre-sized spheroidal hydrogels (SH) with a core-shell structure allowing long term stability in aqueous media. The SH were fabricated by extruding, drop-wise, a cationic cellulose nanofibril (CCNF) dispersion into an oppositely charged polyacrylic acid (PAA) bath. The SH have a solid-like CCNF-PAA shell, acting as a semi-permeable membrane, and a liquid-like CCNF suspension in the core. Swelling behaviour of the SH was dependent on the osmotic pressure of the ageing media. Swelling could be supressed by increasing the ionic strength of the media as this enhanced interfibrillar interactions and thus strengthened the outer gel membrane. We further validated a potential application of SH as re-usable matrixes for glucose oxidase (GOx) entrapment, where the SH work as “microreactors” from which substrate and product are freely able to migrate, through the SH shell whilst avoiding enzyme leakage.	Feb 2020

Instruments / Technical Area

Publication Details

Published

Actions

I22-Small angle scattering & Diffraction

Core-shell spheroidal hydrogels produced via charge-driven interfacial complexation

Vincenzo Calabrese , Davide Califano , Marcelo A. Da Silva , Julien Schmitt , Saffron J. Bryant , Kazi M. Zakir Hossain , Ana Maria Percebom , Aurora Perez-Gramatges , Janet Lesley Scott , Karen J. Edler

Acs Applied Polymer Materials

DOI: 10.1021/acsapm.9b01086

Diamond Proposal Number(s): [20409]