Search Results

You searched for all publications:

with publication states 'Published' 'Published (Approved)'

Search Again...

These results include publications that have not yet been reviewed and processed by Diamond Light Source. To view only processed publications click here.

You can use the folder icon under Actions to collate papers as required. You can then click on View Folder in the left-hand navigation to review and/or download your folder.

Exact matches
Related results

One item found (0 items not approved).1

Instruments / Technical Area	Publication Details	Published	Actions
	The electrophilicity of surface carbon species in the redox of CuO‐CeO2 catalysts Liqun Kang , Bolun Wang , Andreas T. Güntner , Siyuan Xu , Xuhao Wan , Yiyun Liu , Sushila Marlow , Yifei Ren , Diego Gianolio , Chiu C. Tang , Vadim Murzin , Hiroyuki Asakura , Qian He , Shaoliang Guan , Juan J. Velasco-Vélez , Sotiris E. Pratsinis , Yuzheng Guo , Feng Ryan Wang Angewandte Chemie International Edition DOI: 10.1002/anie.202102570 Open Access Show Abstract ▼ Abstract: Electronic metal‐support interaction (EMSI) describes the electron flow between metal sites and a metal oxide support. It is generally used to follow the mechanism of redox reactions. In the study of CuO‐CeO2 redox, an additional flow of electron from metallic Cu to surface carbon species is observed via a combination of operando X‐ray absorption spectroscopy, synchrotron X‐ray powder diffraction, near ambient pressure‐near edge X‐ray absorption fine structure, and diffuse reflectance infrared Fourier transform spectroscopy. An electronic metal‐support‐carbon interaction (EMSCI) is proposed to explain the reaction pathway of CO oxidation. The EMSCI provides a complete picture of the mass and electron flow, which will help predict and improve the catalytic performance in the selective activation of CO2 , carbonate or carbonyl species in C1 chemistry.	Mar 2021

Publications Database

Search Results

You searched for all publications:

Search Again...

Subject Areas (check all that apply) select all

Instruments used to collect data (check all that apply) select all

Collaborations involved (check all that apply) select all

Diamond Offline Facilities used

Relevant Technical Areas (check all that apply) select all

Menu for Anonymous User