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I09-Surface and Interface Structural Analysis	Stabilisation of Li-rich disordered rocksalt oxyfluoride cathodes by particle surface modification Andrew J. Naylor , Ida Kallquist , David Peralta , Jean-Frederic Martin , Adrien Boulineau , Jean-Francois Colin , Christian Baur , Johann Chable , Maximilian Fichtner , Kristina Edstrom , Maria Hahlin , Daniel Brandell Acs Applied Energy Materials DOI: 10.1021/acsaem.0c00839 Diamond Proposal Number(s): [20870] Open Access Show Abstract ▼ Abstract: Promising theoretical capacities and high voltages are offered by Li-rich disordered rocksalt oxyfluoride materials as cathodes in lithium ion batteries. However, as has been discovered for many other Li-rich materials, the oxyfluorides suffer from extensive surface degradation, leading to severe capacity fading. In the case of Li2VO2F, we have previously determined this to be a result of detrimental reactions between an unstable surface layer and the organic electrolyte. Herein, we present the protection of Li2VO2F particles with AlF3 surface modification, resulting in a much enhanced capacity retention over 50 cycles. While the specific capacity for the untreated material drops below 100 mA h g-1 after only 50 cycles, the treated materials retain almost 200 mA h g-1. Photoelectron spectroscopy depth profiling confirms the stabilisation of the active material surface by the surface modification and reveals its suppression of electrolyte decomposition.	May 2020

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