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Formation of an interlocked double-chain from an organic–inorganic [2]rotaxane

DOI: 10.1039/C8CC09339C DOI Help

Authors: Jesus Ferrando Soria (The University of Manchester; Universidad de Valencia) , Antonio Fernandez (The University of Manchester; Loughborough University) , Iñigo J. Vitorica-yrezabal (The University of Manchester) , Deepak Asthana (The University of Manchester) , Christopher A. Muryn (The University of Manchester) , Floriana Tuna (The University of Manchester) , Grigore A. Timco (The University of Manchester) , Richard E. P. Winpenny (The University of Manchester)
Co-authored by industrial partner: No

Type: Journal Paper
Journal: Chemical Communications , VOL 111

State: Published (Approved)
Published: February 2019

Abstract: Here we show that a structure containing a polymeric interlocking daisy chain is obtained from the reaction of an inorganic–organic [2]rotaxane [HB{CrIII7NiII(μ-F)8(O2CtBu)16}], where B is an organic thread terminated with a bi-pyridyl unit, with an oxo-centered metal carboxylate triangle [FeIII2CoII(μ3-O)(O2CtBu)6(HO2CtBu)3].

Subject Areas: Chemistry


Instruments: I19-Small Molecule Single Crystal Diffraction