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Molecular-salt hybrids; integration of ammonia borane into lithium halides
Authors:
Irene
Cascallana-Matias
(University of Glasgow; University of Strathclyde)
,
Joachim
Breternitz
(University of Glasgow)
,
Annabelle
Baker
(Diamond Light Source)
,
Hallam
Davis
(University of Glasgow)
,
Edmund J.
Cussen
(University of Strathclyde)
,
Duncan H.
Gregory
(University of Glasgow)
Co-authored by industrial partner:
No
Type:
Journal Paper
Journal:
Inorganic Chemistry Frontiers
, VOL 6
, PAGES 808 - 812
State:
Published (Approved)
Published:
March 2019
Diamond Proposal Number(s):
13155

Abstract: New molecular-salt-like hybrids contain ammonia borane (AB) in co-existence with lithium halides in single lattices. [LiI](NH3BH3) and [LiI](NH3BH3)2 are members of a generic [LiX]m(AB)n (X = Iā, BH4ā; m, n = integer) materials family which release hydrogen on decomposition and demonstrate Li+-ion conductivity more than two orders of magnitude higher than either LiBH4 or LiI.
Subject Areas:
Chemistry,
Materials
Instruments:
I11-High Resolution Powder Diffraction
Added On:
19/03/2019 11:28
Documents:
hjoo333.pdf
Discipline Tags:
Chemistry
Materials Science
Inorganic Chemistry
Technical Tags:
Diffraction
X-ray Powder Diffraction