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Identification of the key steps in the self-assembly of homogeneous gold metal nanoparticles produced using inverse micelles

DOI: 10.1039/C9CP03473K DOI Help

Authors: Donato Decarolis (University College London; Research Complex at Harwell (RCaH)) , Yaroslav I. Odarchenko (University College London; Research Complex at Harwell (RCaH)) , Jennifer J. Herbert (University College London; Research Complex at Harwell (RCaH); Netherlands Organisation for Scientific Research (NWO)) , Chengwu Qiu (University College London (UCL); Research Complex at Harwell (RCaH)) , Alessandro Longo (Netherlands Organisation for Scientific Research (NWO); Consiglio Nazionale delle Ricerche) , Andrew M. Beale (University College London; Research Complex at Harwell (RCaH))
Co-authored by industrial partner: No

Type: Journal Paper
Journal: Physical Chemistry Chemical Physics , VOL 60

State: Published (Approved)
Published: August 2019

Open Access Open Access

Abstract: The self-assembly of gold nanoparticles (Au NPs) using polymer-encapsulated inverse micelles was studied using a set of advanced X-ray techniques (i.e. XAFS, SAXS) in addition to DLS, UV-vis spectroscopy and TEM. Importantly the combination of these techniques with the inverse micelle approach affords us detailed insight and to rationalize the evolving molecular chemistry and how this drives the formation of the Au NPs. We observe that the mechanism comprises three key steps: an initial fast reduction of molecular Au(III) species to molecular Au(I)Cl; the latter species are often very unstable during the self-assembly process. This is followed by a gradual reduction of these molecular Au(I) species and the formation of sub-nanometric Au clusters which coalesce into nanoparticles. It was also found that addition of small amounts of HCl can accelerate the formation of the Au clusters (the second phase) without affecting the final particle size or its particle size distribution. These findings would help us to understand the reaction mechanism of Au NP formation as well as providing insights into how NP properties could be further tailored for a wide range of practical applications.

Subject Areas: Chemistry

Instruments: B18-Core EXAFS

Other Facilities: ESRF