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Implications of the molybdenum coordination environment in MFI zeolites on methane dehydroaromatisation performance

DOI: 10.1002/cctc.201901166 DOI Help

Authors: Andrew M. Beale (University College London; Research Complex at Harwell) , Miren Agote-Aran (University College; Diamond Light Source) , Rachel E. Fletcher (University College London) , Martha Briceno (Johnson Matthey Technology Centre) , Anna B. Kroner (Diamond Light Source) , Igor V. Sazanov (Central Laser Facility, Research Complex at Harwell) , Ben Slater (University College London) , María E. Rivas (Johnson Matthey Technology Centre) , Andrew W. J. Smith (Johnson Matthey Technology Centre) , Paul Collier (Johnson Matthey Technology Centre) , Ines Lezcano-Gonzalez (University College London; Research Complex at Harwell)
Co-authored by industrial partner: Yes

Type: Journal Paper
Journal: Chemcatchem

State: Published (Approved)
Published: September 2019
Diamond Proposal Number(s): 11623

Abstract: The structure and activity of Mo/Silicalite‐1 (MFI, Si/Al = ∞) were compared to Mo/H‐ZSM‐5 (MFI, Si/Al = 15), a widely studied catalyst for methane dehydroaromatisation (MDA). The anchoring mode of Mo was evaluated by in situ X‐ray absorption spectroscopy (XAS) and density functional theory (DFT). The results showed that in Mo/Silicalite‐1, calcination leads to dispersion of MoO3 precursor into tetrahedral Mo‐oxo species in close proximity to the microporous framework. A weaker interaction of the Mo‐oxo species with the Silicalite‐1 was determined by XAS and DFT. While both catalysts are active for MDA, Mo/Silicalite‐1 undergoes rapid deactivation which was attributed to a faster sintering of Mo species leading to the accumulation of carbon deposits on the zeolite outer surface. The results shed light onto the nature of the Mo structure(s) while evidencing the importance of framework Al in stabilising active Mo species under MDA conditions.

Journal Keywords: MDA; Mo/zeolite; in situ XAS; DFT

Subject Areas: Chemistry

Instruments: B18-Core EXAFS

Added On: 30/09/2019 10:05

Discipline Tags:

Zeolites Physical Chemistry Catalysis Chemistry Organic Chemistry

Technical Tags:

Spectroscopy X-ray Absorption Spectroscopy (XAS) Extended X-ray Absorption Fine Structure (EXAFS)