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Organic cage dumbbells

DOI: 10.1002/chem.201905623 DOI Help

Authors: Rebecca L. Greenaway (University of Liverpool) , Valentina Santolini (Imperial College London) , Filip T. Szczypiński (Imperial College London) , Michael J. Bennison (University of Liverpool) , Marc A. Little (University of Leeds) , Andrew Marsh (University of Liverpool) , Kim E. Jelfs (Imperial College London) , Andrew I. Cooper (University of Liverpool)
Co-authored by industrial partner: No

Type: Journal Paper
Journal: Chemistry – A European Journal , VOL 26 , PAGES 3718 - 3722

State: Published (Approved)
Published: March 2020
Diamond Proposal Number(s): 21726

Abstract: Molecular dumbbells with organic cage capping units were synthesised via a multi‐component imine condensation between a tri‐topic amine and di‐ and tetra‐topic aldehydes. This is an example of self‐sorting, which can be rationalised by computational modelling.

Journal Keywords: aldehydes; amines; cage compounds; imines; topology

Subject Areas: Chemistry

Instruments: I19-Small Molecule Single Crystal Diffraction

Discipline Tags:

Organic Chemistry Chemistry

Technical Tags:

Diffraction Single Crystal X-ray Diffraction (SXRD)