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Photocrystallographic structure determination of a new geometric isomer of [Ru(NH3)4(H2O)(?1-OSO)][MeC6H4SO3]2

DOI: 10.1039/b604039j DOI Help

Authors: Katharine F. Bowes (Department of Chemistry, University of Cambridge, U.K) , Jacqueline M. Cole (Department of Chemistry, University of Cambridge, U.K) , Shamus L. G. Husheer (Department of Chemistry, University of Cambridge, U.K.) , Paul R. Raithby (Department of Chemistry, University of Bath) , Teresa L. Savarese (Department of Chemistry, University of Bath, U.K.) , Hazel A. Sparkes (Department of Chemistry, University of Bath, U.K.) , Simon J. Teat (Diamond Light Source) , John E. Warren (CCLRC Daresbury Laboratory)
Co-authored by industrial partner: No

Type: Journal Paper
Journal: Chemical Communications , PAGES 2248-2250

State: Published (Approved)
Published: May 2006

Abstract: The structure of a new metastable geometric isomer of [Ru(NH3)(4)(H2O)(SO2)][MeC6H4SO3](2) in which the SO2 group is coordinated through a single oxygen in an eta(1)-OSO bonding mode has been determined at 13 K; the new isomer was obtained as a 36% component of the structure within a single crystal upon irradiation using a tungsten lamp.

Subject Areas: Chemistry


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