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Stabilisation of tri-valent ions with vacant coordination site at a corrole-metal interface

DOI: 10.1039/D0CC03947K DOI Help

Authors: Peter S. Deimel (Technical University of Munich) , Pablo Casado Aguilar (Technical University of Munich) , Mateusz Paszkiewicz (Technical University of Munich) , David A. Duncan (Technical University of Munich; Diamond Light Source) , Johannes Barth (Technical University of Munich) , Florian Klappenberger (Technical University of Munich) , Wolfgang Schöfberger (Johannes Kepler University) , Francesco Allegretti (Technical University of Munich)
Co-authored by industrial partner: No

Type: Journal Paper
Journal: Chemical Communications

State: Published (Approved)
Published: August 2020

Abstract: By exploiting an established on-surface metallation strategy, we address the ability of the corrolic macrocycle to stabilise transition metal ions in high-valent (III) oxidation states in metal-supported molecular layers. This approach offers a route to engineer adsorbed metal complexes that cannot be easily fabricated by organic synthesis methods and bear a vacant axial coordination site for catalytic conversions.

Subject Areas: Chemistry

Facility: UE56−2 PGM-2 at BESSY II

Added On: 17/08/2020 14:04

Discipline Tags:

Molecular Complexes Chemistry Organometallic Chemistry

Technical Tags: