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Potassium iodide reduces the stability of triple-cation perovskite solar cells

DOI: 10.1039/D0RA07107B DOI Help

Authors: Tarek I. Alanazi (University of Sheffield; Northern Border University) , Onkar S. Game (University of Sheffield) , Joel A. Smith (University of Sheffield) , Rachel C. Kilbride (University of Sheffield) , Claire Greenland (University of Sheffield) , Rahul Jayaprakash (University of Sheffield) , Kyriacos Georgiou (University of Sheffield) , Nicholas J. Terrill (Diamond Light Source) , David G. Lidzey (University of Sheffield)
Co-authored by industrial partner: No

Type: Journal Paper
Journal: Rsc Advances , VOL 10 , PAGES 40341 - 40350

State: Published (Approved)
Published: November 2020
Diamond Proposal Number(s): 18563

Open Access Open Access

Abstract: The addition of alkali metal halides to hybrid perovskite materials can significantly impact their crystallisation and hence their performance when used in solar cell devices. Previous work on the use of potassium iodide (KI) in active layers to passivate defects in triple-cation mixed-halide perovskites has been shown to enhance their luminescence efficiency and reduce current–voltage hysteresis. However, the operational stability of KI passivated perovskite solar cells under ambient conditions remains largely unexplored. By investigating perovskite solar cell performance with SnO2 or TiO2 electron transport layers (ETL), we propose that defect passivation using KI is highly sensitive to the composition of the perovskite–ETL interface. We reconfirm findings from previous reports that KI preferentially interacts with bromide ions in mixed-halide perovskites, and – at concentrations >5 mol% in the precursor solution – modifies the primary absorber composition as well as leading to the phase segregation of an undesirable secondary non-perovskite phase (KBr) at high KI concentration. Importantly, by studying both material and device stability under continuous illumination and bias under ambient/high-humidity conditions, we show that this secondary phase becomes a favourable degradation product, and that devices incorporating KI have reduced stability.

Diamond Keywords: Photovoltaics; Semiconductors

Subject Areas: Chemistry, Materials, Energy

Instruments: I22-Small angle scattering & Diffraction

Added On: 10/11/2020 08:31


Discipline Tags:

Earth Sciences & Environment Sustainable Energy Systems Energy Climate Change Physical Chemistry Energy Materials Chemistry Materials Science Chemical Engineering Engineering & Technology Perovskites Metallurgy

Technical Tags:

Scattering Wide Angle X-ray Scattering (WAXS) Grazing Incidence Wide Angle Scattering (GIWAXS)