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Synchronous, time resolved, diffuse reflectance FT-IR, energy dispersive EXAFS (EDE) and mass spectrometric investigation of the behaviour of Rh catalysts during NO reduction by CO

DOI: 10.1039/b405694a DOI Help

Authors: Mark A Newton (ESRF) , Bhrat Jyoti (Southampton University) , Andrew Dent (Diamond Light Source Ltd) , Steven G Fiddy (Daresbury Laboratory) , John Evans (University of Southampton)
Co-authored by industrial partner: No

Type: Journal Paper
Journal: Chemical Communications , VOL (21) , PAGES 2382-2383

State: Published (Approved)
Published: September 2004

Abstract: Synchronous, time resolved, infra-red, XAFS, and mass spectroscopies are simultaneously applied in situ to the investigation of the dynamic behaviour of Rh/Al2O3 catalysts during NO reduction by CO; NO conversion, and its kinetic character are closely correlated to the conversion of Rh(I) (predominantly Rh-I(CO)(2)) to Rh(0).

Subject Areas: Chemistry

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Added On: 10/11/2010 08:51

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