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Tracking lithium penetration in solid electrolytes in 3D by in-situ synchrotron X-ray computed tomography

DOI: 10.1016/j.nanoen.2021.105744 DOI Help

Authors: Shuai Hao (University College London; The Faraday Institution) , Sohrab R. Daemi (University College London) , Thomas M. M. Heenan (University College London; The Faraday Institution) , Wenjia Du (University College London) , Chun Tan (University College London) , Malte Storm (Diamond Light Source) , Christoph Rau (Diamond Light Source) , Dan J. I. Brett (University College London; The Faraday Institution) , Paul R. Shearing (University College London; The Faraday Institution)
Co-authored by industrial partner: No

Type: Journal Paper
Journal: Nano Energy , VOL 82

State: Published (Approved)
Published: April 2021
Diamond Proposal Number(s): 22198

Abstract: Solid state batteries have attracted extensive attention, but the lithium penetration through the solid electrolyte remains a critical barrier to commercialisation and is not yet fully understood. In this study, the 3D morphological evolution of cracks with deposited lithium were tracked as they penetrated through the solid electrolyte during repetitive plating. This is achieved by utilising in-situ synchrotron X-ray computed tomography with high spatial and temporal resolutions. Thin-sheet cracks were observed to penetrate the solid electrolyte without immediate short-circuiting of the cell. Changes in their width and volume were quantified. By calculating the volume of deposited lithium, it was found that the lithium was only partially filled in cracks, and its filling ratio quickly dropped from 94.95% after the 1st plating to ca. 20% after the 4th plating. The filling process was revealed through tracking the line profile of grayscale along cracks. It was found that lithium grew much more slowly than cracks, so that the cracks near the cathode side were largely hollow and the cell could continue to operate. The deposited lithium after short circuit was segmented and its distribution was visualised. DVC analysis was applied to map local high stress and strain, which aggregated along cracks and significantly increased at areas where new cracks formed.

Journal Keywords: Lithium dendrite; Crack; Solid electrolyte; In-situ X-ray CT; Morphology

Diamond Keywords: Batteries

Subject Areas: Materials, Chemistry, Energy


Instruments: I13-2-Diamond Manchester Imaging

Discipline Tags:

Energy Energy Storage Material Sciences Energy Materials Chemistry

Technical Tags:

Imaging Tomography