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A [Mn18] wheel-of-wheels

DOI: 10.1039/D1CC00185J DOI Help

Authors: Marco Coletta (The University of Edinburgh) , Thomais G. Tziotzi (The University of Crete) , Mark Gray (The University of Edinburgh) , Gary S. Nichol (The University of Edinburgh) , Mukesh K. Singh (The University of Edinburgh) , Constantinos J. Milios (The University of Crete) , Euan K. Brechin (The University of Edinburgh)
Co-authored by industrial partner: No

Type: Journal Paper
Journal: Chemical Communications , VOL 116 , PAGES 4122-4125

State: Published (Approved)
Published: March 2021
Diamond Proposal Number(s): 22240

Open Access Open Access

Abstract: A [Mn18] wheel of wheels is obtained from the reaction of MnBr2ยท4H2O and LH3 in MeOH. The metallic skeleton reveals two asymmetric [MnIII6MnII2] square wheels connected into a larger wheel via two MnII ions. Magnetic susceptibility and magnetisation data reveal competing exchange interactions, supported by computational studies.

Subject Areas: Chemistry, Materials, Physics


Instruments: I19-Small Molecule Single Crystal Diffraction

Added On: 28/03/2021 14:49

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d1cc00185j.pdf

Discipline Tags:

Materials Science Quantum Materials Physics Magnetism Chemistry

Technical Tags:

Diffraction Small Molecule Diffraction