Publication
Article Metrics
Citations
Online attention
Highly efficient removal of neonicotinoid insecticides by thioether-based (multivariate) metal–organic frameworks
Authors:
Cristina
Negro
(Universidad de Valencia)
,
Héctor
Martínez Pérez-Cejuela
(Universitat de València)
,
Ernesto F.
Simó-Alfonso
(Universitat de València)
,
José Manuel
Herrero-Martínez
(Universitat de València)
,
Rosaria
Bruno
(Università della Calabria)
,
Donatella
Armentano
(Università della Calabria)
,
Jesus
Ferrando-Soria
(Universidad de Valencia)
,
Emilio
Pardo
(Universidad de Valencia)
Co-authored by industrial partner:
No
Type:
Journal Paper
Journal:
Acs Applied Materials & Interfaces
State:
Published (Approved)
Published:
June 2021
Diamond Proposal Number(s):
22411
,
25759
Abstract: Circumventing the impact of agrochemicals on aquatic environments has become a necessity for health and ecological reasons. Herein, we report the use of a family of five eco-friendly water-stable isoreticular metal–organic frameworks (MOFs), prepared from amino acids, as adsorbents for the removal of neonicotinoid insecticides (thiamethoxam, clothianidin, imidacloprid, acetamiprid, and thiacloprid) from water. Among them, the three MOFs containing thioether-based residues show remarkable removal efficiency. In particular, the novel multivariate MOF {SrIICuII6[(S,S)-methox]1.5[(S,S)-Mecysmox]1.50(OH)2(H2O)}·36H2O (5), featuring narrow functional channels decorated with both −CH2SCH3 and −CH2CH2SCH3 thioalkyl chains—from l-methionine and l-methylcysteine amino acid-derived ligands, respectively—stands out and exhibits the higher removal efficiency, being capable to capture 100% of acetamiprid and thiacloprid in a single capture step under dynamic solid-phase extraction conditions—less than 30 s. Such unusual combination of outstanding efficiency, high stability in environmental conditions, and low-cost straightforward synthesis in 5 places this material among the most attractive adsorbents reported for the removal of this type of contaminants.
Journal Keywords: multivariate metal−organic frameworks; amino acids; water remediation; neonicotinoid insecticides; host−guest chemistry
Diamond Keywords: Pesticides
Subject Areas:
Chemistry,
Materials,
Environment
Instruments:
I19-Small Molecule Single Crystal Diffraction
Added On:
14/06/2021 20:28
Discipline Tags:
Desertification & Pollution
Earth Sciences & Environment
Agriculture & Fisheries
Chemistry
Materials Science
Metal-Organic Frameworks
Life Sciences & Biotech
Metallurgy
Organometallic Chemistry
Technical Tags:
Diffraction
Single Crystal X-ray Diffraction (SXRD)