Publication

Article Metrics

Citations


Online attention

Extending the Pore Size of Crystalline Metal Phosphonates toward the Mesoporous Regime by Isoreticular Synthesis

DOI: 10.1021/ja1097995 DOI Help

Authors: Michael Wharmby (Diamond Light Source) , John Mowat (University of St Andrews) , Stephen Thompson (Diamond Light Source) , Paul Wright (University of St Andrews)
Co-authored by industrial partner: No

Type: Journal Paper
Journal: Journal Of The American Chemical Society , VOL 133 (5)

State: Published (Approved)
Published: January 2011
Diamond Proposal Number(s): 6269

Abstract: Crystalline microporous cobalt and nickel bisphosphonates with a hexagonal array of one-dimensional channels 1.8 nm in diameter have been prepared hydrothermally and provide the first example of the use of isoreticular chemistry in the synthesis of phosphonate metal-organic frameworks. The materials contain both physisorbed and coordinating water molecules in the as-prepared form, but these can be removed to give permanent extra-large microporosity, with pore volumes of up to 0.68 cm3 g-1, and coordinatively unsaturated sites, with concentrations up to 4.25 mmol g-1.

Subject Areas: Chemistry


Instruments: I11-High Resolution Powder Diffraction

Discipline Tags:



Technical Tags: