Sustainable and efficient low‐energy light emitters: a series of one‐dimensional d10 coinage Metal Organic Chalcogenolates, [M(o‐SPhCO2H)]n

DOI: 10.1002/cptc.202200030

Authors: Oleksandra Veselska (CNRS) , Nathalie Guillou (CNRS) , Maria Diaz-Lopez (Diamond Light Source) , Pierre Bordet (CNRS) , Gilles Ledoux (CNRS) , Sébastien Lebègue (University of Lorraine:) , Adel Mesbah (CNRS) , Alexandra Fateeva (Universite Claude Bernard Lyon 1) , Aude Demessence (CNRS - Lyon University)
Co-authored by industrial partner: No

Type: Journal Paper
Journal: Chemphotochem

State: Published (Approved)
Published: February 2022

Abstract: A series of d 10 coinage metal thiosalicylate coordination polymers (CPs) is reported. The 1D structures of the three CPs are formed by M 3 S 3 fused hexagons for Cu and Ag compounds and interpenetrated helical chains for Au CP. Depending on the metal, solid state red and NIR emissive CPs are obtained with QY up to 50%, providing a great opportunity to replace the actual emissive Critical Raw Materials.

Journal Keywords: coordination polymer; thiolate ligand; photoluminescence; NIR

Subject Areas: Materials, Chemistry

Facility: ID15A at ESRF; LUCIA at Soleil

Added On: 16/02/2022 10:03

Discipline Tags:

Energy Materials Chemistry Materials Science Metal-Organic Frameworks Polymer Science Organometallic Chemistry

Technical Tags: