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Exploring a metalloligand for construction of an oxamato-based metal-organic framework

DOI: 10.1080/00958972.2022.2125303 DOI Help

Authors: Javier Navarro-Alapont (Universitat de Valencia) , Donatella Armentano (Università della Calabria) , Emilio Pardo (Universidad de Valencia) , Jesus Ferrando-Soria (Universitat de Valencia)
Co-authored by industrial partner: No

Type: Journal Paper
Journal: Journal Of Coordination Chemistry , VOL 341 , PAGES 1 - 11

State: Published (Approved)
Published: September 2022
Diamond Proposal Number(s): 22411

Abstract: We report the two-step synthesis of a heterobimetallic oxamato-based metal-organic framework (MOF). First, we prepared an oxamato functionalized carbazole-based dinuclear copper(II) complex, K4{Cu2(carbox)2]}·8H2O, where the carbozale linkers exhibited an uncommon substitution pattern, carbox = N,N’-1,6-carbazolebis(oxamate). Then, this building block was used as a metalloligand toward manganese(II) metal ions to assemble a neutral three-dimensional (3 D) MOF with formula [Mn2Cu2(carbox)2(H2O)4]·6CH3OH·2H2O (1) and single-crystal X-ray diffraction determined the structure. The resulting network constitutes one of the few examples of oxamato-based 3 D MOF.

Subject Areas: Chemistry, Materials

Instruments: I19-Small Molecule Single Crystal Diffraction

Added On: 21/09/2022 17:27

Discipline Tags:

Chemistry Materials Science Metal-Organic Frameworks Metallurgy Organometallic Chemistry

Technical Tags:

Diffraction Single Crystal X-ray Diffraction (SXRD)