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A Mesoporous Metal-Organic Framework Constructed from a Nanosized C3-Symmetric Linker and [Cu24(isophthalate)24] Cuboctahedra

DOI: 10.1039/C1CC13170B DOI Help

Authors: Yong Yan (University of Nottingham, U.K.) , Sihai Yang (University of Nottingham, U.K.) , William Lewis (University of Nottingham, U.K.) , Eric Poirier (Optimal Inc, Michigan, USA.) , Neil Champness (University of Nottingham, U.K.) , Martin Schroder (University of Nottingham, U.K.) , Sarah Barnett (Diamond Light Source) , Alexander Blake (University of Nottingham, U.K.)
Co-authored by industrial partner: Yes

Type: Journal Paper
Journal: Chemical Communications , VOL 47 , PAGES 9995-9997

State: Published (Approved)
Published: July 2011
Diamond Proposal Number(s): 6410

Abstract: The mesoporous framework [Cu3(L)(H2O)3]·(DMF)35·(H2O)35 (NOTT-119) shows on desolvation a BET surface area of 4118(200) m2 g?1, a pore volume of 2.35 cm3 g?1, a total H2 uptake of 101 mg g?1 at 60 bar, 77 K and a total CH4 uptake of 327 mg g?1 at 80 bar, 298 K.

Journal Keywords: Metal-Organic Framework; Gas Storage

Subject Areas: Chemistry, Materials, Energy

Instruments: I19-Small Molecule Single Crystal Diffraction

Added On: 18/07/2011 19:48

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