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Highly porous and robust scandium-based metal–organic frameworks for hydrogen storage

DOI: 10.1039/c1cc11168j DOI Help

Authors: Ilich Ibarra (University of Nottingham) , Sihai Yang (University of Nottingham) , Xiang Lin (University of Nottingham) , Alexander J. Blake (University of Nottingham) , Pierre Rizkallah (Cardiff University) , Harriott Nowell (Diamond Light Source) , Neil R. Champness (University of Nottingham) , Peter Hubberstey (University of Nottingham) , Martin Schröder (University of Nottingham) , David R. Allan (Diamond Light Source)
Co-authored by industrial partner: No

Type: Journal Paper
Journal: Chemical Communications , VOL 47 (29) , PAGES 8304-8306

State: Published (Approved)
Published: June 2011
Diamond Proposal Number(s): 6410

Abstract: The metal–organic frameworks NOTT-400 and NOTT-401, based on a binuclear [Sc2(?2-OH)(O2CR)4] building block, have been synthesised and characterised; the desolvated framework NOTT-401a shows a BET surface area of 1514 m2 g?1 with a total H2 uptake of 4.44 wt% at 77 K and 20 bar.

Journal Keywords: Mof; Scandium; Gas Storage

Subject Areas: Chemistry, Materials, Energy


Instruments: I19-Small Molecule Single Crystal Diffraction

Added On: 26/07/2011 09:03

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