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Expanded-ring and backbone-functionalised N-heterocyclic carbenes
Authors:
Manuel
Iglesias
(Cardiff University)
,
Dirk J.
Beetstra
(Cardiff University)
,
Kingsley J.
Cavell
(Cardiff University)
,
Athanasia
Dervisi
(Cardiff University)
,
Ian A.
Fallis
(Cardiff University)
,
Benson M.
Kariuki
(University of Cardiff)
,
Ross W.
Harrington
(Newcastle University)
,
William
Clegg
(Newcastle University)
,
Peter
Horton
(University of Southampton)
,
Simon
Coles
(University of Southampton)
,
Michael B.
Hursthouse
(Southampton University)
Co-authored by industrial partner:
No
Type:
Journal Paper
Journal:
European Journal Of Inorganic Chemistry
, VOL 2010 (11)
, PAGES 1604-1607
State:
Published (Approved)
Published:
June 2010
Diamond Proposal Number(s):
987
Abstract: An unsaturated seven-membered amidinium salt 7 decomposes in the presence of metal salts under basic conditions. However, 7 readily forms a Diels–Alder cycloadduct with CpH from which the RhI complexes may be prepared. Thus, structurally elaborate, sterically crowded carbene ligand complexes bearing peripheral unsaturated functionality are available in a short versatile synthesis.
Journal Keywords: Carbene Ligands; Cycloaddition; Rhodium; Ligand Design; Isomers
Subject Areas:
Chemistry
Instruments:
I19-Small Molecule Single Crystal Diffraction
Added On:
08/09/2011 12:29
Discipline Tags:
Physical Chemistry
Catalysis
Chemistry
Organometallic Chemistry
Technical Tags:
Diffraction
Single Crystal X-ray Diffraction (SXRD)