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A chiral, self-catenating and porous metal-organic framework and its post-synthetic metal-uptake

DOI: 10.1002/anie.201200758 DOI Help
PMID: 22488777 PMID Help

Authors: Michaele J. Hardie (University of Leeds, U.K.) , Tia Jacobs (University of Leeds, U.K.) , Rob Clowes (University of Liverpool, U.K.) , Andrew Cooper (University of Liverpool, U.K.)
Co-authored by industrial partner: No

Type: Journal Paper
Journal: Angewandte Chemie International Edition , VOL 51 (21) , PAGES 5192-5195

State: Published (Approved)
Published: April 2012
Diamond Proposal Number(s): 7180

Abstract: Free vacancies: A robust and porous metal–organic framework material with unique 4-connected self-catenating structure of {85⋅10} topology was synthesized. The structure features empty bipyridine metal-chelating sites that can be doped with copper cations in a single-crystal-to-single-crystal post-synthetic modification (see picture; scale bar 20 μm).

Journal Keywords: metal doping; metal\u2013organic frameworks; network topologies; nitrogen sorption; post-synthetic modification

Subject Areas: Chemistry

Instruments: I19-Small Molecule Single Crystal Diffraction

Added On: 23/03/2012 16:42

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