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Pressure-induced Jahn-Teller switching in a Mn(12) nanomagnet

DOI: 10.1039/b923962f DOI Help

Authors: Pascal Parois (WestCHEM, Department of Chemistry, University of Glasgow, U.K.) , Javier Sanchez-benitez (School of Chemistry and Centre for Science at Extreme Conditions, University of Edinburgh, U.K.) , Konstantin V. Kamenev (School of Chemistry and Centre for Science at Extreme Conditions, University of Edinburgh, U.K.) , Alistair Lennie (Diamond Light Source) , John Warren (Daresbury laboratory, U.K.) , Euan K. Brechin (School of Chemistry and Centre for Science at Extreme Conditions, University of Edinburgh, U.K.) , Simon Parsons (School of Chemistry and Centre for Science at Extreme Conditions, University of Edinburgh, U.K.) , Mark Murrie (University of Glasgow, U.K.) , Stephen Moggach (School of Chemistry and Centre for Science at Extreme Conditions, University of Edinburgh, U.K.)
Co-authored by industrial partner: No

Type: Journal Paper
Journal: Chemical Communications , VOL 46 (11) , PAGES 1881-1883

State: Published (Approved)
Published: January 2010

Abstract: Pressure-induced switching of a fast-relaxing single-molecule magnet to a slow-relaxing isomer is observed for the first time by using a combination of high pressure single-crystal X-ray diffraction and high pressure magnetic measurements.

Subject Areas: Chemistry

Facility: SRS

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