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Behavior of Aluminum, Arsenic, and Vanadium during the Neutralization of Red Mud Leachate by HCl, Gypsum, or Seawater

DOI: 10.1021/es4010834 DOI Help

Authors: Ian T. Burke (University of Leeds) , Caroline Peacock (University of Leeds) , Cindy Lockwood (University of Leeds) , Douglas Stewart (University of Leeds) , Robert J. G. Mortimer (University of Leeds) , Michael B. Ward (University of Leeds) , Philip Renforth (University of Oxford) , Katalin Gruiz (Budapest University of Technology and Economics) , Will Mayes (Centre for Environmental and Marine Sciences)
Co-authored by industrial partner: No

Type: Journal Paper
Journal: Environmental Science & Technology , VOL 47 (12) , PAGES 6527-6535

State: Published (Approved)
Published: June 2013
Diamond Proposal Number(s): 7525

Abstract: Red mud leachate (pH 13) collected from Ajka, Hungary is neutralized to < pH 10 by HCl, gypsum, or seawater addition. During acid neutralization >99% Al is removed from solution during the formation of an amorphous boehmite-like precipitate and dawsonite. Minor amounts of As (24%) are also removed from solution via surface adsorption of As onto the Al oxyhydroxides. Gypsum addition to red mud leachate results in the precipitation of calcite, both in experiments and in field samples recovered from rivers treated with gypsum after the October 2010 red mud spill. Calcite precipitation results in 86% Al and 81% As removal from solution, and both are nonexchangeable with 0.1 mol Lā€“1 phosphate solution. Contrary to As associated with neoformed Al oxyhydroxides, EXAFS analysis of the calcite precipitates revealed only isolated arsenate tetrahedra with no evidence for surface adsorption or incorporation into the calcite structure, possibly as a result of very rapid As scavenging by the calcite precipitate. Seawater neutralization also resulted in carbonate precipitation, with >99% Al and 74% As removed from solution during the formation of a poorly ordered hydrotalcite phase and via surface adsorption to the neoformed precipitates, respectively. Half the bound As could be remobilized by phosphate addition, indicating that As was weakly bound, possibly in the hydrotalcite interlayer. Only 5ā€“16% V was removed from solution during neutralization, demonstrating a lack of interaction with any of the neoformed precipitates. High V concentrations are therefore likely to be an intractable problem during the treatment of red mud leachates.

Subject Areas: Environment, Chemistry

Instruments: I18-Microfocus Spectroscopy

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