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Utility of tris(4-bromopyridyl) europium complexes as versatile intermediates in the divergent synthesis of emissive chiral probes

DOI: 10.1039/c4dt00253a DOI Help

Authors: Stephen J. Butler (Durham University) , Martina Delbianco (Durham University) , Nicholas H. Evans (Durham University) , Andrew T. Frawley (Durham University) , Robert Pal (Durham University) , David Parker (Durham University) , Robert S. Puckrin (Durham University) , Dmitry Yufit (Durham University)
Co-authored by industrial partner: No

Type: Journal Paper
Journal: Dalton Transactions , VOL 43 (15) , PAGES 5721-5730

State: Published (Approved)
Published: February 2014
Diamond Proposal Number(s): 8682

Abstract: The synthetic utility of europium complexes with three coordinated 4-bromopyridyl groups for chromophore elaboration has been assessed in palladium-catalysed Sonogashira coupling reactions, and in copper(I) mediated click reactions of the triazide derivative, generated in situ.

Subject Areas: Chemistry, Materials

Instruments: I19-Small Molecule Single Crystal Diffraction

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