"Converting" an hexametallic MnIII wheel to a dodecametallic MnIII wheel via ligand oximation

DOI: 10.1039/c3cc49583c

Authors: Sergio Sanz (University of Edinburgh) , Jamie M. Frost (University of Edinburgh) , Mateusz Pitak (University of Southampton) , Simon Coles (University of Southampton) , Stergios Piligkos (University of Copenhagen) , Paul J. Lusby (University of Edinburgh) , Euan K. Brechin (University of Edinburgh)
Co-authored by industrial partner: No

Type: Journal Paper
Journal: Chemical Communications , VOL 50

State: Published (Approved)
Published: February 2014
Diamond Proposal Number(s): 8521

Abstract: Ligand oximation "converts' an hexametallic MnIII wheel into a dodecametallic MnIII wheel, while the magnetic exchange switches from ferro- to antiferromagnetic.

Subject Areas: Chemistry, Physics


Instruments: I19-Small Molecule Single Crystal Diffraction

Added On: 26/03/2014 12:34

Discipline Tags:

Physics Physical Chemistry Chemistry Magnetism

Technical Tags:

Diffraction Single Crystal X-ray Diffraction (SXRD)