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An Aluminophosphate Molecular Sieve with 36 Crystallographically Distinct Tetrahedral Sites

DOI: 10.1002/anie.201402495 DOI Help
PMID: 24862164 PMID Help

Authors: Jun Kyu Lee (POSTECH, Pohang) , Alessandro Turrina (University of St Andrews) , Liangkui Zhu (Jilin University, Changchun) , Seungwan Seo (POSTECH, Pohang) , Daliang Zhang (Jilin University, Changchun) , Paul A. Cox (University of Portsmouth) , Paul Wright (University of St Andrews) , Shilun Qiu (Jilin University, Changchun) , Suk Bong Hong (POSTECH, Pohang)
Co-authored by industrial partner: No

Type: Journal Paper
Journal: Angewandte Chemie International Edition , VOL 53 (29) , PAGES 7480 - 7483

State: Published (Approved)
Published: July 2014
Diamond Proposal Number(s): 9027

Abstract: The structure of the new medium-pore alumino- phosphate molecular sieve PST-6 is determined by the combined use of rotation electron diffraction tomography, synchrotron X-ray powder diffraction, and computer model- ing. PST-6 was prepared by calcination of another new aluminophosphate material with an unknown structure syn- thesized using diethylamine as a structure-directing agent, which is thought to contain bridging hydroxy groups. PST-6 has 36 crystallographically distinct tetrahedral sites in the asymmetric unit and is thus crystallographically the most complex zeolitic structure ever solved.

Subject Areas: Chemistry


Instruments: I11-High Resolution Powder Diffraction

Other Facilities: Pohang Accelerator Laboratory, Korea

Added On: 30/10/2014 16:51

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