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Tuning of gallery heights in a crystalline 2D carbon nitride network
DOI:
10.1039/c2ta01068b
Authors:
Sam
Chong
(University of Liverpool)
,
James T. A.
Jones
(University of Liverpool, U.K.)
,
Yaroslav Z.
Khimyak
(University of East Anglia, U.K.)
,
Andrew I.
Cooper
(University of Liverpool, U.K.)
,
Arne
Thomas
(Technische Universität Berlin, Germany)
,
Markus
Antonietti
(Max Planck Institute of Colloids and Interfaces, Germany)
,
Michael
Bojdys
(University of Liverpool)
Co-authored by industrial partner:
No
Type:
Journal Paper
Journal:
Journal Of Materials Chemistry A
, VOL 1 (4)
, PAGES 1102-1107
State:
Published (Approved)
Published:
November 2012
Abstract: Poly(triazine imide)a 2D layered networkcan be obtained as an intercalation compound with halides from the ionothermal condensation of dicyandiamide in a eutectic salt melt. The gallery height of the intercalated material can be tuned via the composition of the eutectic melt and by post-synthetic modification. Here, we report the synthesis of poly(triazine imide) with intercalated bromide ions (PTI/Br) from a lithium bromide and potassium bromide salt melt.
Subject Areas:
Chemistry
Instruments:
I11-High Resolution Powder Diffraction