Tuning of gallery heights in a crystalline 2D carbon nitride network

DOI: 10.1039/c2ta01068b

Authors: Sam Chong (University of Liverpool) , James T. A. Jones (University of Liverpool, U.K.) , Yaroslav Z. Khimyak (University of East Anglia, U.K.) , Andrew I. Cooper (University of Liverpool, U.K.) , Arne Thomas (Technische Universität Berlin, Germany) , Markus Antonietti (Max Planck Institute of Colloids and Interfaces, Germany) , Michael Bojdys (University of Liverpool)
Co-authored by industrial partner: No

Type: Journal Paper
Journal: Journal Of Materials Chemistry A , VOL 1 (4) , PAGES 1102-1107

State: Published (Approved)
Published: November 2012

Abstract: Poly(triazine imide)—a 2D layered network—can be obtained as an intercalation compound with halides from the ionothermal condensation of dicyandiamide in a eutectic salt melt. The gallery height of the intercalated material can be tuned via the composition of the eutectic melt and by post-synthetic modification. Here, we report the synthesis of poly(triazine imide) with intercalated bromide ions (PTI/Br) from a lithium bromide and potassium bromide salt melt.

Subject Areas: Chemistry


Instruments: I11-High Resolution Powder Diffraction

Added On: 08/11/2014 19:22

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