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PZT-like structural phase transitions in the BiFeO3-KNbO3 solid solution

DOI: 10.1039/C5DT00140D DOI Help

Authors: Donna Arnold (University of Kent) , Robert Lennox (University of Kent) , Laura Vera Stimpson (University of Kent) , Mark Price (University of Kent) , Daniel Taylor (University of Maryland) , Efrain E Rodriguez (University of Maryland) , Gavin B. G. Stenning (ISIS Neutron and Muon Source) , Marek Jura (STFC)
Co-authored by industrial partner: No

Type: Journal Paper
Journal: Dalton Transactions

State: Published (Approved)
Published: April 2015
Diamond Proposal Number(s): 9194

Abstract: Despite the high prominence of the perovskites BiFeO3 and KNbO3 the solid solution between the two has received little attention. We report a detailed neutron and synchrotron X-ray powder diffraction, and Raman spectroscopy study which demonstrates an R3c → P4mm → Amm2 series of structural phase transitions similar to that exhibited by the PbZrO3–PbTiO3 solid solution.

Diamond Keywords: Ferroelectricity; Antiferromagnetic

Subject Areas: Materials, Chemistry


Instruments: I11-High Resolution Powder Diffraction

Other Facilities: HRPD at ISIS

Added On: 07/04/2015 09:28

Discipline Tags:

Quantum Materials Multiferroics Physical Chemistry Chemistry Materials Science Inorganic Chemistry Perovskites Metallurgy

Technical Tags:

Diffraction X-ray Powder Diffraction