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A high-pressure crystallographic and magnetic study of Na
Authors:
Gavin A.
Craig
(University of Glasgow)
,
Christopher
Woodall
(University of Edinburgh)
,
Scott
Mckellar
(University of Edinburgh)
,
Mike
Probert
(Newcastle University)
,
Konstantin
Kamenev
(University of Edinburgh)
,
Stephen
Moggach
(University of Edinburgh)
,
Euan K.
Brechin
(University of Edinburgh)
,
Simon
Parsons
(University of Edinburgh)
,
Mark
Murrie
(University of Glasgow)
Co-authored by industrial partner:
No
Type:
Journal Paper
Journal:
Dalton Transactions
State:
Published (Approved)
Published:
September 2015
Diamond Proposal Number(s):
10392

Abstract: The crystal structure and magnetic properties of the compound Na5[Mn(L-tart)2]·12H2O (1, L-tart = L-tartrate) have been investigated over the pressure range 0.34–3.49 GPa. The bulk modulus of 1 has been determined as 23.9(6) GPa, with a compression of the coordination spheres around the Na+ ions observed. 1 is therefore relatively incompressible, helping it to retain its magnetic anisotropy under pressure.
Subject Areas:
Chemistry
Instruments:
I19-Small Molecule Single Crystal Diffraction
Added On:
19/10/2015 17:04
Documents:
c5dt03320a.pdf
Discipline Tags:
Physical Chemistry
Chemistry
Technical Tags:
Diffraction
High Pressure Single Crystal Diffraction