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Cerium-based metal organic frameworks with UiO-66 architecture: synthesis, properties and redox catalytic activity

DOI: 10.1039/C5CC02606G DOI Help

Authors: Martin Lammert (University of Kiel) , Michael Wharmby (Diamond Light Source) , Simon Smolders (KULeuven) , Bart Bueken (KULeuven) , Alexandra Lieb (Otto-von-Guericke-Universit├Ąt Magdeburg) , Kirill A. Lomachenko (Turin University) , Dirk De Vos (KULeuven) , Norbert Stock (University of Kiel)
Co-authored by industrial partner: No

Type: Journal Paper
Journal: Chemical Communications , VOL 51 , PAGES 12578 - 12581

State: Published (Approved)
Published: July 2015

Abstract: A series of nine Ce(IV)-based metal organic frameworks with the UiO-66 structure containing linker molecules of different sizes and functionalities were obtained under mild synthesis conditions and short reaction times. Thermal and chemical stabilities were determined and a Ce-UiO-66-BDC/TEMPO system was successfully employed for the aerobic oxidation of benzyl alcohol.

Subject Areas: Chemistry

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Added On: 11/01/2016 12:38

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