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Time-Resolved X-ray Absorption Spectroscopy Data for the Study of Chemical Reaction Intermediate States

DOI: 10.1063/1.2644682 DOI Help

Authors: Sofia Diaz-moreno (Diamond Light Source) , Daniel Bowron (ISIS Facility, Rutherford Appleton Laboratory) , John Evans (University of Southampton)
Co-authored by industrial partner: No

Type: Conference Paper
Conference: X-ray Absorption Fine Structure-XAFS 13, AIP Conference Proceedings, 882, p. 849-851
Peer Reviewed: Yes

State: Published (Approved)
Published: February 2007

Abstract: Energy-dispersive X-ray absorption Spectroscopy is an increasingly powerful tool for the investigation of kinetic processes in chemical systems as an element-specific local structure and electronic-state probe. In this paper we present a study of the structural evolution of the inner-sphere electron transfer reaction between [IrCl6]2- and [Co(CN)5]3-. The experimental requirements necessary for the extraction of maximal structural and electronic information are discussed.

Journal Keywords: Energy Dispersive EXAFS; Reaction Intermediates

Subject Areas: Chemistry, Technique Development

Facility: ESRF