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Structural Investigation of the bridged activated complex in the reaction between hexachloroiridate(IV) and pentacyanocobaltate(II).

DOI: 10.1039/b507738a DOI Help
PMID: 16471065 PMID Help

Authors: Sofia Diaz-moreno (Diamond Light Source) , Daniel Bowron (ISIS Facility, Rutherford Appleton Laboratory) , John Evans (University of Southampton)
Co-authored by industrial partner: No

Type: Journal Paper
Journal: Dalton Transactions , PAGES 3814

State: Published (Approved)
Published: September 2005

Abstract: Time resolved energy dispersive X-ray absorption spectroscopy has been used to follow the structural evolution of the inner-sphere electron transfer reaction between [IrCl6]2? and [Co(CN)5]3?, and to characterise the local structure of the iridium metal centre in the bridged activated complex formed during the reaction.

Journal Keywords: Bridge Activated Complex; X-Ray Absorption Spectroscopy; Energy Dispersive Exafs

Subject Areas: Chemistry

Facility: ESRF