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Synthesis of a novel zeolite through a pressure-induced reconstructive phase transition process

DOI: 10.1002/anie.201305230 DOI Help

Authors: Jose Luis Jorda Moret (Instituto de Tecnología Química) , Fernando Rey (Instituto de Tecnología Química) , German Sastre (Instituto de Tecnología Química) , Susana Valencia (Instituto de Tecnología Química) , Miguel Palomino (Instituto de Tecnología Química) , Avelino Corma (Instituto de Tecnología Química) , Alfredo Segura (Universidad de Valencia) , Daniel Errandonea (Universidad de Valencia) , Raul Lacomba Perales (Universidad de Valencia) , Francisco Javier Manjon Herrera (Universitat Politècnica de València) , Oscar Gomis (Universidad Politécnica de Valencia) , Annette Kleppe (Diamond Light Source) , Andrew Jephcoat (Diamond Light Source) , Monica Amboage (Diamond Light Source) , J. Alberto Rodríguez-Velamazán (Instituto de Ciencia de Materiales de Aragón (CSIC-Universidad de Zaragoza) at Institute Laue-Langevin)
Co-authored by industrial partner: No

Type: Journal Paper
Journal: Angewandte Chemie International Edition , VOL 52 (40) , PAGES 10458 - 10462

State: Published (Approved)
Published: September 2013

Abstract: The first pressure-induced solid-phase synthesis of a zeolite has been found through compression of a common zeolite, ITQ-29 (see scheme, Si yellow, O red). The new microporous structure, ITQ-50, has a unique structure and improved performance for propene/propane separation with respect the parent material ITQ-29.

Journal Keywords: Adsorption; high-pressure chemistry; phase transitions; X-ray diffraction; zeolites

Diamond Keywords: Gas Separation

Subject Areas: Chemistry, Materials

Instruments: I15-Extreme Conditions

Other Facilities: D1B at ILL

Added On: 02/03/2016 14:01

Discipline Tags:

Zeolites Physical Chemistry Chemistry Materials Science Inorganic Chemistry

Technical Tags:

Diffraction High-Pressure X-ray Diffraction (HP-XRD)