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Neutral iodotriazole foldamers as tetradentate halogen bonding anion receptors

DOI: 10.1039/C7CC00727B DOI Help

Authors: Arseni Borissov (University of Oxford) , Jason Y. C. Lim (University of Oxford) , Asha Brown (University of Oxford) , Kirsten E. Christensen (University of Oxford) , Amber Thompson (University of Oxford) , Martin D. Smith (University of Oxford) , Paul D. Beer (University of Oxford)
Co-authored by industrial partner: No

Type: Journal Paper
Journal: Chem. Commun.

State: Published (Approved)
Published: February 2017
Diamond Proposal Number(s): 13639

Abstract: Neutral tetradentate halogen bond donor foldamers were synthesised and exhibit enhanced anion affinities over their hydrogen bonding analogues, displaying iodide selectivity over lighter halide, carboxylate and dihydrogen phosphate anions. A foldamer with a chiral (S)-binaphthol motif was demonstrated to distinguish between enantiomers of chiral anions.

Subject Areas: Chemistry

Instruments: I19-Small Molecule Single Crystal Diffraction

Added On: 13/02/2017 10:57

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