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Co-based single-molecule magnet confined in the barium phosphate apatite matrix with a high energy barrier for magnetization relaxation

DOI: 10.1039/C7CC02453C DOI Help

Authors: Pavel E Kazin (Lomonosov Moscow State University) , Mikhail A. Zykin (Lomonosov Moscow State University) , Lev A. Trusov (Lomonosov Moscow State University) , Artem A. Eliseev (Lomonosov Moscow State University) , Oxana Magdysyuk (Diamond Light Source) , Robert Dinnebier (Max Planck Institute for Solid State Research, Stuttgart) , Reinhard Kremer (Max Planck Institute for Solid State Research) , Claudia Felser (Max Planck Institute for Chemical Physics of Solids) , Martin Jansen (Max Planck Institute for Solid State Research; Max Planck Institute for Chemical Physics of Solids)
Co-authored by industrial partner: No

Type: Journal Paper
Journal: Chem. Commun.

State: Published (Approved)
Published: April 2017
Diamond Proposal Number(s): 14465

Abstract: An apatite-type barium phosphate with high content of cobalt ions in the trigonal channels features slow relaxation of magnetization with an energy barrier Ueff of up to 387 cm-1 which is well above the values for all so far known d-metal based single-molecule magnets (SMMs).

Subject Areas: Chemistry, Materials


Instruments: I12-JEEP: Joint Engineering, Environmental and Processing