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XMCD and XMCD-PEEM Studies on Magnetic-Field-Assisted Self-Assembled 1D Nanochains of Spherical Ferrite Particles

DOI: 10.1002/adfm.201701265 DOI Help

Authors: Wen Zhang (Southeast University, Nanjing; National University of Singapore) , Ping Kwan Johnny Wong (National University of Singapore; University of Twente) , Dong Zhang (Southeast University, Nanjing) , Jinjin Yue (Southeast University, Nanjing) , Zhaoxia Kou (Southeast University, Nanjing) , Gerrit Van Der Laan (Diamond Light Source) , Andreas Scholl , Jian-guo Zheng (University of California Irvine) , Zuhong Lu (Southeast University, Nanjing) , Ya Zhai (Southeast University, Nanjing)
Co-authored by industrial partner: No

Type: Journal Paper
Journal: Advanced Functional Materials , VOL 290 , PAGES 1701265

State: Published (Approved)
Published: May 2017

Abstract: Quasi-1D nanochains of spherical magnetic ferrite particles with a homogeneous particle size of ≈200 nm and a micrometer-sized chain length are fabricated via a self-assembly method under an external magnetic field. This assisting magnetic field (H_assist), applied during synthesis, significantly modifies the distribution of the Fe2+ Oh, Fe3+ Td, and Fe3+ Oh cations in the chains, as demonstrated by X-ray magnetic circular dichroism (XMCD) combined with theoretical analysis. This provides direct evidence of the nontrivial role of external synthetic conditions for defining the crystal chemistry of nanoscale ferrites and in turn their magnetic properties, providing an extra degree of freedom for intentional control over the performances of 1D magnetic nanodevices for various applications. Magnetic imaging, performed via XMCD in photoemission electron microscopy, further shows the possibility of creating and trapping a series of adjacent magnetic domain walls in a single chain, suggesting that there is great application potential for these nanochains in 1D magnetic nanodevices, as determined by field- or currentdriven domain wall motions. Practical control over the magnetic properties of the nanochains is also achieved by extrinsic dopants of cobalt and zinc, which are observed to occupy the ferrite ionic sites in a selective manner.

Journal Keywords: nanoscience, XMCD, ferrites, magnetic imaging

Subject Areas: Physics, Materials, Information and Communication Technology

Facility: ALS