Discovery of a novel, large pore phase in a bimetallic Al/V metal-organic framework

DOI: 10.1039/C7TA08103K

Authors: Hannes Depauw (Ghent University) , Irena Nevjestic (Ghent University) , Guangbo Wang (Ghent University) , Karen Leus (Ghent University) , Freddy Callens (Ghent University) , Els De Canck (Ghent University) , Klaartje De Buysser (Ghent University) , Henk M. Vrielinck (Ghent University) , Pascal Van Der Voort (Ghent University)
Co-authored by industrial partner: No

Type: Journal Paper
Journal: Journal Of Materials Chemistry A

State: Published (Approved)
Published: October 2017
Diamond Proposal Number(s): 12401

Abstract: A new series of bimetallic COMOC-2(V)/DUT-5(Al) frameworks are developed and fully characterized. Electron paramagnetic resonance and transmission electron microscopy confirm the homogeneous dispersion of Al/V in the entire framework. The study of the flexibility by means of CO2 pressure dependent XRD and high pressure sorption reveals the co-existence of two different large and a narrow pore phase in the entire pressure regime.

Subject Areas: Materials, Chemistry


Instruments: I11-High Resolution Powder Diffraction

Added On: 24/10/2017 09:47

Discipline Tags:

Chemistry Materials Science Metal-Organic Frameworks Metallurgy Organometallic Chemistry

Technical Tags:

Diffraction X-ray Powder Diffraction