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Monitoring the formation of PtNi nanoalloys supported on hollow graphitic spheres using in situ pair distribution function analysis

DOI: 10.1039/C7CP07840D DOI Help

Authors: S. Ortatatli (Max-Planck-Institut für Kohlenforschung) , J. Knossalla (Max-Planck-Institut für Kohlenforschung) , F. Schüth (Max-Planck-Institut für Kohlenforschung) , C. Weidenthaler (Max-Planck-Institut für Kohlenforschung)
Co-authored by industrial partner: No

Type: Journal Paper
Journal: Physical Chemistry Chemical Physics , VOL 14

State: Published (Approved)
Published: January 2018
Diamond Proposal Number(s): 14028

Open Access Open Access

Abstract: This article aims to address the formation and the structural disordering/ordering phenomena of PtNi nanoalloys supported on hollow graphitic spheres (HGSs) using pair distribution function (PDF) analysis under ex situ/in situ data collection conditions. Starting from small nanoparticles (10–15 Å in diameter) embedded in HGSs, structural changes were monitored during stepwise heating and cooling of the sample using in situ PDF analysis. In order to evaluate the conventional synthesis route for the production of PtNi nanoalloys supported on HGSs, ex situ PDF experiments were performed before and after heat treatment in a furnace. The studies demonstrate that the local structure of the in situ synthesised PtNi nanoalloy differs from its ex situ synthesised counterpart. A partially ordered PtNi nanoalloy was obtained during the stepwise in situ cooling of the precursor, whereas the conventional ex situ synthesis route did not lead to the formation of an ordered crystal structure. In this study we could show that rapid heating and cooling results in a disordered PtNi alloy whereas slow heating and cooling leads to disorder–order transitions in PtNi.

Subject Areas: Materials, Chemistry, Energy

Instruments: I15-Extreme Conditions

Other Facilities: ESRF


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