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Single-crystal-to-single-crystal postsynthetic modification of a metal–organic framework via ozonolysis

DOI: 10.1021/jacs.7b12913 DOI Help

Authors: Jorge Albalad (Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC and The Barcelona Institute of Science and Technology) , Heng Xu (Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC and The Barcelona Institute of Science and Technology) , Felipe Gándara (Materials Science Factory, Instituto de Ciencia de Materiales de Madrid (ICMM), Consejo Superior de Investigaciones Científicas (CSIC)) , Mohamed Haouas (Université Paris-Saclay) , Charlotte Martineau-Corcos (Université Paris-Saclay; CNRS) , Rubén Mas-Ballesté (Universidad Autónoma de Madrid) , Sarah A. Barnett (Diamond Light Source) , Judith Juanhuix (ALBA Synchrotron) , Inhar Imaz (Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC and The Barcelona Institute of Science and Technology) , Daniel Maspoch (Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC and The Barcelona Institute of Science and Technology; ICREA)
Co-authored by industrial partner: No

Type: Journal Paper
Journal: Journal Of The American Chemical Society

State: Published (Approved)
Published: January 2018

Abstract: We describe solid-gas phase, single-crystal-to-single-crystal, post-synthetic modifications of a Metal-Organic Framework (MOF). Using ozone, we quantitatively transformed the olefin groups of a UiO-66-type MOF into 1,2,4-trioxolane rings, which we then selectively converted into either aldehydes or carboxylic acids.

Journal Keywords: Organic acids; Redox reactions; Aldehydes; Organic reactions; Metal organic frameworks

Subject Areas: Chemistry, Materials


Instruments: I19-Small Molecule Single Crystal Diffraction

Added On: 29/01/2018 09:34

Discipline Tags:

Chemistry Materials Science Metal-Organic Frameworks Metallurgy Organometallic Chemistry

Technical Tags:

Diffraction Single Crystal X-ray Diffraction (SXRD)