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Monitoring Photo-induced Population Dynamics in Metastable Linkage Isomer Crystals: A Crystallographic Kinetic Study of [Pd(Bu4dien)NO2]BPh4

DOI: 10.1039/C7CP05422J DOI Help

Authors: Lauren E. Hatcher (University of Bath) , Jonathan M. Skelton (University of Bath) , Mark R. Warren (Diamond Light Source) , Clare Stubbs (University of Bath) , Estelina Lora Da Silva (University of Bath) , Paul R. Raithby (University of Bath)
Co-authored by industrial partner: No

Type: Journal Paper
Journal: Physical Chemistry Chemical Physics

State: Published (Approved)
Published: January 2018
Diamond Proposal Number(s): 8567 , 9734 , 13698

Open Access Open Access

Abstract: We present a detailed kinetic study of photo-induced solid state linkage isomerism in the compound [Pd(Bu4dien)NO2]BPh4 (Bu4dien = N,N,N’,N’-tetrabutyldiethylenetriamine) using in-situ photocrystallographic techniques. We explore the key variables that influence the photoconversion and develop a detailed kinetic model for the excitation and decay processes and the temperature dependence of the conversion rates. We show that by varying the temperature the lifetime of the excited state can be varied over orders of magnitude, making these systems ideal test cases for the development of new time-resolved X-ray diffraction methods. The kinetic model is used to build a numerical-simulation tool, which we use to explore the practicalities of pump-probe single-crystal diffraction experiments with minute and second time-resolution.

Subject Areas: Technique Development, Chemistry, Physics

Instruments: I19-Small Molecule Single Crystal Diffraction