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Molecular trefoil knot from a trimeric circular helicate

DOI: 10.1021/jacs.8b00738 DOI Help

Authors: Liang Zhang (University of Manchester) , David P. August (University of Manchester) , Jiankang Zhong (University of Manchester) , George F. S. Whitehead (University of Manchester) , IƱigo J. Vitorica-Yrezabal (University of Manchester) , David A. Leigh (University of Manchester)
Co-authored by industrial partner: No

Type: Journal Paper
Journal: Journal Of The American Chemical Society

State: Published (Approved)
Published: March 2018
Diamond Proposal Number(s): 8977 , 12745

Abstract: We report the two-step synthesis of a molecular trefoil knot in 90% overall yield through the self-assembly of a 12-component trimeric circular zinc helicate followed by ring closing metathesis of six pendant alkene chains. Both the trimeric circular helicate intermediate and the resulting trefoil knot were characterized by NMR spectroscopy, mass spectrometry, and X-ray crystallography.

Journal Keywords: Zinc; Metals; Ligands; Crystal structure; Mathematical methods

Subject Areas: Chemistry, Materials

Instruments: I19-Small Molecule Single Crystal Diffraction

Added On: 20/03/2018 14:04

Discipline Tags:

Chemistry Materials Science Chemical Engineering Engineering & Technology Metallurgy

Technical Tags:

Diffraction Single Crystal X-ray Diffraction (SXRD)