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Tunable Prussian blue analogues for the selective synthesis of propargylamines through A 3 coupling

DOI: 10.1039/C8CY00073E DOI Help

Authors: Carlos Marquez (KU Leuven) , Francisco G. Cirujano (KU Leuven) , Cédric Van Goethem (KU Leuven) , Ivo Vankelecom (KU Leuven) , Dirk De Vos (KU Leuven) , Trees De Baerdemaeker (KU Leuven)
Co-authored by industrial partner: No

Type: Journal Paper
Journal: Catalysis Science & Technology , VOL 125

State: Published (Approved)
Published: March 2018
Diamond Proposal Number(s): 13284

Open Access Open Access

Abstract: M1[Co(CN)6]2/3-type Prussian blue analogues (M1–Co PBAs) were studied as catalysts for the synthesis of propargylamines via A3 coupling of phenylacetylene, benzaldehyde and piperidine. Cu0.86Zn0.14–Co PBA was the best catalyst for the reaction by combining the high conversion obtained with Cu–Co PBA with the excellent selectivity obtained with Zn–Co PBA.

Subject Areas: Chemistry, Materials

Instruments: I11-High Resolution Powder Diffraction

Added On: 11/04/2018 11:37


Discipline Tags:

Physical Chemistry Catalysis Chemistry Materials Science

Technical Tags:

Diffraction X-ray Powder Diffraction