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Tunable Prussian blue analogues for the selective synthesis of propargylamines through A 3 coupling
Authors:
Carlos
Marquez
(KU Leuven)
,
Francisco G.
Cirujano
(KU Leuven)
,
Cédric
Van Goethem
(KU Leuven)
,
Ivo
Vankelecom
(KU Leuven)
,
Dirk
De Vos
(KU Leuven)
,
Trees
De Baerdemaeker
(KU Leuven)
Co-authored by industrial partner:
No
Type:
Journal Paper
Journal:
Catalysis Science & Technology
, VOL 125
State:
Published (Approved)
Published:
March 2018
Diamond Proposal Number(s):
13284

Abstract: M1[Co(CN)6]2/3-type Prussian blue analogues (M1–Co PBAs) were studied as catalysts for the synthesis of propargylamines via A3 coupling of phenylacetylene, benzaldehyde and piperidine. Cu0.86Zn0.14–Co PBA was the best catalyst for the reaction by combining the high conversion obtained with Cu–Co PBA with the excellent selectivity obtained with Zn–Co PBA.
Subject Areas:
Chemistry,
Materials
Instruments:
I11-High Resolution Powder Diffraction
Added On:
11/04/2018 11:37
Documents:
C8CY00073E.pdf
Discipline Tags:
Physical Chemistry
Catalysis
Chemistry
Materials Science
Technical Tags:
Diffraction
X-ray Powder Diffraction